Valorization of long-neglected spruce bark and bark-press effluents through integrated utilization of stilbenoids and pectin

Jinze Dou; Evgen Multia; Xinyue Dong; Lei Wang; Tapani Vuorinen

doi:10.1016/j.cej.2023.144122

Valorization of long-neglected spruce bark and bark-press effluents through integrated utilization of stilbenoids and pectin

Jinze Dou^*
, Evgen Multia
, Xinyue Dong
, Lei Wang^*
, Tapani Vuorinen

^*Tämän työn vastaava kirjoittaja

Westlake University

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

7 Sitaatiot (Scopus)

134 Lataukset (Pure)

Abstrakti

Wood bark has exclusively been used for energy at pulp mills, while long-neglected, this huge biomass resource has great potential for valorization. To maximize its value in new ways, here we propose using both fresh (industrial) spruce bark and its bark-press effluents as sustainable sources of natural stilbenoids and pectin. Ultrafiltration removed approximately 90% of the high molecular weight polyphenols as well as enriched stilbenoids from bark-press effluents. Based on a techno-economic analysis, the forest industry would obtain greater revenue potential up to €100 per ton of bark by processing bark side streams compared to their traditional combustion-based strategy if implementing the improved debarking technology. Overall the valorization of stilbenoids and pectin from bark-press effluents or spruce bark offers a promising strategy to produce bio-based, high-value UV-filter ingredients as alternatives to fossil-based ones, and high-grade pectin in an economic feasible and potentially environmentally friendly bolt-on process to the existing mills.

Alkuperäiskieli	Englanti
Artikkeli	144122
Sivumäärä	10
Julkaisu	Chemical Engineering Journal
Vuosikerta	470
Varhainen verkossa julkaisun päivämäärä	18 kesäk. 2023
DOI - pysyväislinkit	https://doi.org/10.1016/j.cej.2023.144122
Tila	Julkaistu - 15 elok. 2023
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Rahoitus

This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Metsä Spring Oy and Dr. Suurnakki Anna from Metsä Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitkänen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo Kääriäinen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization. This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Metsä Spring Oy and Dr. Suurnakki Anna from Metsä Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitkänen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo Kääriäinen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization.

YK:n kestävän kehityksen tavoitteet

Tämä tuotos edistää seuraavia kestävän kehityksen tavoitteita:

SDG 9 – Teollisuus, innovaatiot ja infrastruktuuri
SDG 12 – Vastuullinen kulutus ja tuotanto
SDG 13 – Ilmastotoimet
SDG 15 – Maanpäällinen elämä

Pääsy asiakirjaan

10.1016/j.cej.2023.144122Lisenssi: CC BY

CHEM_Dou_et_al_Valorization_of_long-neglected_2023_Chemical_Engineering_JournalFinal published version, 5,99 MBLisenssi: CC BY

Muut tiedostot ja linkit

Linkki julkaisuun Scopuksessa

FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future
Mäkelä, K. (Vastuullinen johtaja)
01/05/2018 → 31/12/2022
Projekti: Academy of Finland: Other research funding

Raaka-aineiden tutkimusinfrastruktuuri
Karppinen, M. (Manager)
Kemian tekniikan korkeakoulu
Laitteistot/tilat: Facility

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@article{0ff0086cc60b412697705cff2951d982,

title = "Valorization of long-neglected spruce bark and bark-press effluents through integrated utilization of stilbenoids and pectin",

abstract = "Wood bark has exclusively been used for energy at pulp mills, while long-neglected, this huge biomass resource has great potential for valorization. To maximize its value in new ways, here we propose using both fresh (industrial) spruce bark and its bark-press effluents as sustainable sources of natural stilbenoids and pectin. Ultrafiltration removed approximately 90\% of the high molecular weight polyphenols as well as enriched stilbenoids from bark-press effluents. Based on a techno-economic analysis, the forest industry would obtain greater revenue potential up to €100 per ton of bark by processing bark side streams compared to their traditional combustion-based strategy if implementing the improved debarking technology. Overall the valorization of stilbenoids and pectin from bark-press effluents or spruce bark offers a promising strategy to produce bio-based, high-value UV-filter ingredients as alternatives to fossil-based ones, and high-grade pectin in an economic feasible and potentially environmentally friendly bolt-on process to the existing mills.",

keywords = "Bark-press effluents, Pectin, Pulp and paper industry, Spruce bark, Stilbenoids, Techno-economic analysis",

author = "Jinze Dou and Evgen Multia and Xinyue Dong and Lei Wang and Tapani Vuorinen",

note = "Funding Information: This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Mets{\"a} Spring Oy and Dr. Suurnakki Anna from Mets{\"a} Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitk{\"a}nen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo K{\"a}{\"a}ri{\"a}inen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization. Funding Information: This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Mets{\"a} Spring Oy and Dr. Suurnakki Anna from Mets{\"a} Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitk{\"a}nen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo K{\"a}{\"a}ri{\"a}inen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization. Publisher Copyright: {\textcopyright} 2023 The Author(s)",

year = "2023",

month = aug,

day = "15",

doi = "10.1016/j.cej.2023.144122",

language = "English",

volume = "470",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

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TY - JOUR

T1 - Valorization of long-neglected spruce bark and bark-press effluents through integrated utilization of stilbenoids and pectin

AU - Dou, Jinze

AU - Multia, Evgen

AU - Dong, Xinyue

AU - Wang, Lei

AU - Vuorinen, Tapani

N1 - Funding Information: This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Metsä Spring Oy and Dr. Suurnakki Anna from Metsä Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitkänen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo Kääriäinen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization. Funding Information: This work made use of the RawMatTERS Finland infrastructure (RAMI) facilities based at Aalto University. This work was a part of the Academy of Finland's Flagship Programme under Projects No. 318890 and No. 318891 (Competence Centre for Materials Bioeconomy, FinnCERES). Industrial support and advising is gratefully acknowledged to Dr. Kemppainen Katariina from Metsä Spring Oy and Dr. Suurnakki Anna from Metsä Fibre Oy. From Aalto University, Dr. Heidi Henrickson provided English-language proofreading. Dr. Leena Pitkänen provided the assistance for the molecular weight analysis using GPC. Appreciation is also extended to team SBARK (Megan McGlynn, Chiao-wen Hsu, Iines Jakovlev, Eveliina Juuri, Nina Riutta, Aarni Tujula), Prof. Pirjo Kääriäinen, and Eeva Suorlahti from Aalto University CHEMARTS for providing high quality photographs of spruce tree. Liu Zhongqi from Westlake University assisted with image visualization. Publisher Copyright: © 2023 The Author(s)

PY - 2023/8/15

Y1 - 2023/8/15

N2 - Wood bark has exclusively been used for energy at pulp mills, while long-neglected, this huge biomass resource has great potential for valorization. To maximize its value in new ways, here we propose using both fresh (industrial) spruce bark and its bark-press effluents as sustainable sources of natural stilbenoids and pectin. Ultrafiltration removed approximately 90% of the high molecular weight polyphenols as well as enriched stilbenoids from bark-press effluents. Based on a techno-economic analysis, the forest industry would obtain greater revenue potential up to €100 per ton of bark by processing bark side streams compared to their traditional combustion-based strategy if implementing the improved debarking technology. Overall the valorization of stilbenoids and pectin from bark-press effluents or spruce bark offers a promising strategy to produce bio-based, high-value UV-filter ingredients as alternatives to fossil-based ones, and high-grade pectin in an economic feasible and potentially environmentally friendly bolt-on process to the existing mills.

AB - Wood bark has exclusively been used for energy at pulp mills, while long-neglected, this huge biomass resource has great potential for valorization. To maximize its value in new ways, here we propose using both fresh (industrial) spruce bark and its bark-press effluents as sustainable sources of natural stilbenoids and pectin. Ultrafiltration removed approximately 90% of the high molecular weight polyphenols as well as enriched stilbenoids from bark-press effluents. Based on a techno-economic analysis, the forest industry would obtain greater revenue potential up to €100 per ton of bark by processing bark side streams compared to their traditional combustion-based strategy if implementing the improved debarking technology. Overall the valorization of stilbenoids and pectin from bark-press effluents or spruce bark offers a promising strategy to produce bio-based, high-value UV-filter ingredients as alternatives to fossil-based ones, and high-grade pectin in an economic feasible and potentially environmentally friendly bolt-on process to the existing mills.

KW - Bark-press effluents

KW - Pectin

KW - Pulp and paper industry

KW - Spruce bark

KW - Stilbenoids

KW - Techno-economic analysis

UR - https://www.scopus.com/pages/publications/85162084309

U2 - 10.1016/j.cej.2023.144122

DO - 10.1016/j.cej.2023.144122

M3 - Article

AN - SCOPUS:85162084309

SN - 1385-8947

VL - 470

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 144122

ER -

Valorization of long-neglected spruce bark and bark-press effluents through integrated utilization of stilbenoids and pectin

Abstrakti

Rahoitus

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future

Laitteet

Raaka-aineiden tutkimusinfrastruktuuri

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