Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration

Valentina Guccini; Josphat Phiri; Jon Trifol; Ville Rissanen; Seyede Maryam Mousavi; Jaana Vapaavuori; Tekla Tammelin; Thaddeus Maloney; Eero Kontturi

doi:10.1021/acsapm.1c01430

Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration

Valentina Guccini^*, Josphat Phiri, Jon Trifol, Ville Rissanen, Seyede Maryam Mousavi, Jaana Vapaavuori, Tekla Tammelin, Thaddeus Maloney, Eero Kontturi^*

^*Tämän työn vastaava kirjoittaja

VTT Technical Research Centre of Finland Ltd.

Tutkimustuotos: Lehtiartikkeli › Letter › Scientific › vertaisarvioitu

13 Sitaatiot (Scopus)

136 Lataukset (Pure)

Abstrakti

Osmotic dehydration (OD) was introduced as a method to reproducibly tune the water content and porosity of cellulose nanofiber (CNF) hydrogels. The hierarchical porosity was followed by electron microscopy (pores with a >100 μm diameter) and thermoporosimetry (mesopores), together with mechanical testing, in hydrogels with solid contents ranging from 0.7 to 12 wt %. Furthermore, a reciprocal correlation between proton conductivity and the ratio of water bound to the nanocellulose network was established, suggesting the potential of these systems toward tunable energy materials.

Alkuperäiskieli	Englanti
Sivut	24-28
Sivumäärä	5
Julkaisu	ACS Applied Polymer Materials
Vuosikerta	4
Numero	1
Varhainen verkossa julkaisun päivämäärä	22 jouluk. 2021
DOI - pysyväislinkit	https://doi.org/10.1021/acsapm.1c01430
Tila	Julkaistu - 14 tammik. 2022
OKM-julkaisutyyppi	B1 Kirjoitus tieteellisessä aikakauslehdessä

YK:n kestävän kehityksen tavoitteet

Tämä tuotos edistää seuraavia kestävän kehityksen tavoitteita:

Pääsy asiakirjaan

10.1021/acsapm.1c01430Lisenssi: CC BY

CHEM_Guccini_et_al_Tuning_the_Porosity_2022_ACS_Applied_Polymer_MaterialsFinal published version, 2,66 MBLisenssi: CC BY

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1 Aktiivinen
3 Päättynyt

ModelCom: Autonomously adapting and communicating modular textiles
Vapaavuori, J. (Vastuullinen tutkija)
01/01/2021 → 31/12/2025
Projekti: EU_H2ERC
FuturoLeaf: Leaf-inspired nanocellulose frameworks for next generation photosynthetic cell factories
Kontturi, E. (Vastuullinen tutkija)
01/09/2020 → 31/12/2023
Projekti: EU_HEFWP
-: Lignoselluloosasta ja yhteyttävistä soluista valmistettu hiilidioksidia sitova ja lehtirakennetta jäljittelevä biokatalyyttialusta
Kontturi, E. (Vastuullinen tutkija)
01/09/2019 → 31/08/2023
Projekti: Academy of Finland: Other research funding

OtaNano
Rissanen, A. (Manager)
Aalto-yliopisto
Laitteistot/tilat: Facility
OtaNano Nanomikroskopiakeskus
Seitsonen, J. (Manager) & Rissanen, A. (Other)
OtaNano
Laitteistot/tilat: Facility
Raaka-aineiden tutkimusinfrastruktuuri
Karppinen, M. (Manager)
Kemian tekniikan korkeakoulu
Laitteistot/tilat: Facility

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title = "Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration",

abstract = "Osmotic dehydration (OD) was introduced as a method to reproducibly tune the water content and porosity of cellulose nanofiber (CNF) hydrogels. The hierarchical porosity was followed by electron microscopy (pores with a >100 μm diameter) and thermoporosimetry (mesopores), together with mechanical testing, in hydrogels with solid contents ranging from 0.7 to 12 wt %. Furthermore, a reciprocal correlation between proton conductivity and the ratio of water bound to the nanocellulose network was established, suggesting the potential of these systems toward tunable energy materials.",

author = "Valentina Guccini and Josphat Phiri and Jon Trifol and Ville Rissanen and Mousavi, {Seyede Maryam} and Jaana Vapaavuori and Tekla Tammelin and Thaddeus Maloney and Eero Kontturi",

note = "| openaire: EC/H2020/899576/EU//FuturoLEAF | openaire: EC/H2020/949648/EU//ModelCom V.G. and E.K. would like to acknowledge the Academy of Finland (AoF) for the Financial support by the Project AlgaLEAF (Project 322755). V.R. and T.T. would like to acknowledge the European Union via the project FuturoLEAF (European Union{\textquoteright}s Horizon 2020 research and innovation programme under grant agreement no. 899576). J.P. and T.M. would like to acknowledge the Foundation for Research of Natural Resources in Finland. M.M. and J.V. would like to acknowledge the European Commission for generous funding for the ModelCom project. J.T. would like to acknowledge the AoF{\textquoteright}s Flagship Programme, Projects . 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). This work utilized facilities provided by the RawMatters Finland Infrastructure (RAMI) at Aalto University, supported by AoF, and the facilities and technical support of the OtaNano Nanomicroscopy Center (Aalto-NMC).",

year = "2022",

month = jan,

day = "14",

doi = "10.1021/acsapm.1c01430",

language = "English",

volume = "4",

pages = "24--28",

journal = "ACS Applied Polymer Materials",

issn = "2637-6105",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration

AU - Guccini, Valentina

AU - Phiri, Josphat

AU - Trifol, Jon

AU - Rissanen, Ville

AU - Mousavi, Seyede Maryam

AU - Vapaavuori, Jaana

AU - Tammelin, Tekla

AU - Maloney, Thaddeus

AU - Kontturi, Eero

N1 - | openaire: EC/H2020/899576/EU//FuturoLEAF | openaire: EC/H2020/949648/EU//ModelCom V.G. and E.K. would like to acknowledge the Academy of Finland (AoF) for the Financial support by the Project AlgaLEAF (Project 322755). V.R. and T.T. would like to acknowledge the European Union via the project FuturoLEAF (European Union’s Horizon 2020 research and innovation programme under grant agreement no. 899576). J.P. and T.M. would like to acknowledge the Foundation for Research of Natural Resources in Finland. M.M. and J.V. would like to acknowledge the European Commission for generous funding for the ModelCom project. J.T. would like to acknowledge the AoF’s Flagship Programme, Projects . 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). This work utilized facilities provided by the RawMatters Finland Infrastructure (RAMI) at Aalto University, supported by AoF, and the facilities and technical support of the OtaNano Nanomicroscopy Center (Aalto-NMC).

PY - 2022/1/14

Y1 - 2022/1/14

N2 - Osmotic dehydration (OD) was introduced as a method to reproducibly tune the water content and porosity of cellulose nanofiber (CNF) hydrogels. The hierarchical porosity was followed by electron microscopy (pores with a >100 μm diameter) and thermoporosimetry (mesopores), together with mechanical testing, in hydrogels with solid contents ranging from 0.7 to 12 wt %. Furthermore, a reciprocal correlation between proton conductivity and the ratio of water bound to the nanocellulose network was established, suggesting the potential of these systems toward tunable energy materials.

AB - Osmotic dehydration (OD) was introduced as a method to reproducibly tune the water content and porosity of cellulose nanofiber (CNF) hydrogels. The hierarchical porosity was followed by electron microscopy (pores with a >100 μm diameter) and thermoporosimetry (mesopores), together with mechanical testing, in hydrogels with solid contents ranging from 0.7 to 12 wt %. Furthermore, a reciprocal correlation between proton conductivity and the ratio of water bound to the nanocellulose network was established, suggesting the potential of these systems toward tunable energy materials.

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U2 - 10.1021/acsapm.1c01430

DO - 10.1021/acsapm.1c01430

M3 - Letter

SN - 2637-6105

VL - 4

SP - 24

EP - 28

JO - ACS Applied Polymer Materials

JF - ACS Applied Polymer Materials

IS - 1

ER -

Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration

Abstrakti

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

ModelCom: Autonomously adapting and communicating modular textiles

FuturoLeaf: Leaf-inspired nanocellulose frameworks for next generation photosynthetic cell factories

-: Lignoselluloosasta ja yhteyttävistä soluista valmistettu hiilidioksidia sitova ja lehtirakennetta jäljittelevä biokatalyyttialusta

Laitteet

OtaNano

OtaNano Nanomikroskopiakeskus

Raaka-aineiden tutkimusinfrastruktuuri

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