Time-Dependent Behavior of Waste Lithium-Ion Batteries in Secondary Copper Smelting

Anna Klemettinen*, Lassi Klemettinen, Radosław Michallik, Hugh O'Brien, Ari Jokilaakso

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

44 Lataukset (Pure)

Abstrakti

As the electrification sector expands rapidly, the demand for metals used in batteries is increasing significantly. New approaches for lithium-ion battery (LIB) recycling have to be investigated and new technologies developed in order to secure the future supply of battery metals (i.e., lithium, cobalt, nickel). In this work, the possibility of integrating LIB recycling with secondary copper smelting was further investigated. The time-dependent behavior of battery metals (Li, Co, Ni, Mn) in simulated secondary copper smelting conditions was investigated for the first time. In the study, copper alloy was used as a medium for collecting valuable metals and the distribution coefficients of these metals between copper alloy and slag were used for evaluating the recycling efficiencies. The determined distribution coefficients follow the order Ni >> Co >> Mn > Li throughout the time range investigated. In our study, the evolution of phases and their chemical composition were investigated in laboratory-scale experiments under reducing conditions of oxygen partial pressure p(O2) = 10−10 atm, at 1300 °C. The results showed that already after 1 h holding time, the major elements were in equilibrium. However, based on the microstructural observations and trace elements distributions, the required full equilibration time for the system was determined to be 16 h.

AlkuperäiskieliEnglanti
Artikkeli190
Sivumäärä13
JulkaisuBatteries
Vuosikerta8
Numero10
DOI - pysyväislinkit
TilaJulkaistu - lokak. 2022
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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