Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes

Janina Hakanpää; Kirsi Yliniemi; Benjamin Wilson; Matti Putkonen; Sarah Höhn; Eero Kontturi; Sannakaisa Virtanen; Lasse Murtomäki

doi:10.1149/2.1231802jes

Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes

Janina Hakanpää, Kirsi Yliniemi, Benjamin Wilson, Matti Putkonen, Sarah Höhn, Eero Kontturi, Sannakaisa Virtanen, Lasse Murtomäki

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

291 Lataukset (Pure)

Abstrakti

Cation transport through a cellulose acetate-poly(N,N-dimethylaminoethyl methacrylate) membrane (CA:PDMAEMA) was studied with scanning electrochemical microscope (SECM) and the thickness increase of the membrane was monitored with ellipsometry. Upon addition of the polyelectrolyte PDMAEMA, the permeability of the probe cation (ferrocenium methanol, FcMeOH) was increased as much as 40-fold. Soaking membranes in an electrolyte solution doubled the permeability in plain CA membranes, whereas for PDMAEMA containing membranes the opposite was observed and the permeability was reduced by 20–40%. This time-dependent behavior is shown to be a result of the presence of PDMAEMA within the membrane matrix, thus providing an interesting platform for controllable membrane permeability.

Alkuperäiskieli	Englanti
Sivut	H39-H44
Sivumäärä	6
Julkaisu	Journal of the Electrochemical Society
Vuosikerta	165
Numero	2
DOI - pysyväislinkit	https://doi.org/10.1149/2.1231802jes
Tila	Julkaistu - 2 helmik. 2018
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu
Tapahtuma	Electrochemical Society Meeting - New Orleans, Yhdysvallat Kesto: 28 toukok. 2017 → 2 kesäk. 2017 Konferenssinumero: 231 http://www.electrochem.org/231

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10.1149/2.1231802jesLisenssi: CC BY-NC-ND

J. Electrochem. Soc.-2018-Hakanpää-H39-44
© The Author(s) 2018. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.1231802jes]
Final published version, 832 KBLisenssi: CC BY-NC-ND

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title = "Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes",

abstract = "Cation transport through a cellulose acetate-poly(N,N-dimethylaminoethyl methacrylate) membrane (CA:PDMAEMA) was studied with scanning electrochemical microscope (SECM) and the thickness increase of the membrane was monitored with ellipsometry. Upon addition of the polyelectrolyte PDMAEMA, the permeability of the probe cation (ferrocenium methanol, FcMeOH) was increased as much as 40-fold. Soaking membranes in an electrolyte solution doubled the permeability in plain CA membranes, whereas for PDMAEMA containing membranes the opposite was observed and the permeability was reduced by 20–40%. This time-dependent behavior is shown to be a result of the presence of PDMAEMA within the membrane matrix, thus providing an interesting platform for controllable membrane permeability.",

author = "Janina Hakanp{\"a}{\"a} and Kirsi Yliniemi and Benjamin Wilson and Matti Putkonen and Sarah H{\"o}hn and Eero Kontturi and Sannakaisa Virtanen and Lasse Murtom{\"a}ki",

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Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes. / Hakanpää, Janina; Yliniemi, Kirsi ; Wilson, Benjamin; Putkonen, Matti; Höhn, Sarah; Kontturi, Eero; Virtanen, Sannakaisa; Murtomäki, Lasse.

julkaisussa: Journal of the Electrochemical Society, Vuosikerta 165, Nro 2, 02.02.2018, s. H39-H44.

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

TY - JOUR

T1 - Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes

AU - Hakanpää, Janina

AU - Yliniemi, Kirsi

AU - Wilson, Benjamin

AU - Putkonen, Matti

AU - Höhn, Sarah

AU - Kontturi, Eero

AU - Virtanen, Sannakaisa

AU - Murtomäki, Lasse

N1 - Conference code: 231

PY - 2018/2/2

Y1 - 2018/2/2

N2 - Cation transport through a cellulose acetate-poly(N,N-dimethylaminoethyl methacrylate) membrane (CA:PDMAEMA) was studied with scanning electrochemical microscope (SECM) and the thickness increase of the membrane was monitored with ellipsometry. Upon addition of the polyelectrolyte PDMAEMA, the permeability of the probe cation (ferrocenium methanol, FcMeOH) was increased as much as 40-fold. Soaking membranes in an electrolyte solution doubled the permeability in plain CA membranes, whereas for PDMAEMA containing membranes the opposite was observed and the permeability was reduced by 20–40%. This time-dependent behavior is shown to be a result of the presence of PDMAEMA within the membrane matrix, thus providing an interesting platform for controllable membrane permeability.

AB - Cation transport through a cellulose acetate-poly(N,N-dimethylaminoethyl methacrylate) membrane (CA:PDMAEMA) was studied with scanning electrochemical microscope (SECM) and the thickness increase of the membrane was monitored with ellipsometry. Upon addition of the polyelectrolyte PDMAEMA, the permeability of the probe cation (ferrocenium methanol, FcMeOH) was increased as much as 40-fold. Soaking membranes in an electrolyte solution doubled the permeability in plain CA membranes, whereas for PDMAEMA containing membranes the opposite was observed and the permeability was reduced by 20–40%. This time-dependent behavior is shown to be a result of the presence of PDMAEMA within the membrane matrix, thus providing an interesting platform for controllable membrane permeability.

U2 - 10.1149/2.1231802jes

DO - 10.1149/2.1231802jes

M3 - Article

VL - 165

SP - H39-H44

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

SN - 0013-4651

IS - 2

T2 - Electrochemical Society Meeting

Y2 - 28 May 2017 through 2 June 2017

ER -

Time-Dependent Behavior of Cation Transport through Cellulose Acetate-Cationic Polyelectrolyte Membranes

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