Thermodynamic Assessment of Liquid Fe-Ni-C Alloy Using Modified Quasichemical Model

Min Paek; Junmo Jeon; Manas Paliwal; Arijit Biswas; Daniel Lindberg; Jong-Jin Pak

doi:10.1007/s11837-020-04487-9

Thermodynamic Assessment of Liquid Fe-Ni-C Alloy Using Modified Quasichemical Model

Min Paek, Junmo Jeon, Manas Paliwal, Arijit Biswas, Daniel Lindberg, Jong-Jin Pak

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

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Abstrakti

The liquid solution properties in the Fe-Ni and Fe-Ni-C systems have been thermodynamically assessed using the modified quasichemical model in the pair approximation. The asymmetry of the Fe-Ni and Fe-Ni-C alloy melts was verified by measuring the melting points of Fe-Ni binary alloys on the Ni-rich side, and the C solubility limit in Fe-Ni melt over the entire concentration range at 1500°C and 1600°C. The solubility minimum of C and the maximum partial enthalpy of mixing of C in the ternary Fe-Ni-C system occurred at near the maximum short-range ordering composition of the binary Fe-Ni liquid solution. The extrema of the partial properties of C in the ternary Fe-Ni-C system were successfully reproduced with only one constant adjustable ternary parameter.

Alkuperäiskieli	Englanti
Sivut	679-687
Sivumäärä	9
Julkaisu	JOM
Vuosikerta	73
Numero	2
Varhainen verkossa julkaisun päivämäärä	25 marrask. 2020
DOI - pysyväislinkit	https://doi.org/10.1007/s11837-020-04487-9
Tila	Julkaistu - helmik. 2021
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

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10.1007/s11837-020-04487-9Lisenssi: CC BY

Paek2021_Article_ThermodynamicAssessmentOfLiquiFinal published version, 915 KBLisenssi: CC BY

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SYMMET (TDM)
Lindberg, D., Attah-Kyei, D., Klemettinen, A., Jeon, J., Paek, M., Avarmaa, K. & Santoso, I.
01/11/2018 → 31/10/2020
Projekti: Business Finland: Other research funding

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title = "Thermodynamic Assessment of Liquid Fe-Ni-C Alloy Using Modified Quasichemical Model",

abstract = "The liquid solution properties in the Fe-Ni and Fe-Ni-C systems have been thermodynamically assessed using the modified quasichemical model in the pair approximation. The asymmetry of the Fe-Ni and Fe-Ni-C alloy melts was verified by measuring the melting points of Fe-Ni binary alloys on the Ni-rich side, and the C solubility limit in Fe-Ni melt over the entire concentration range at 1500°C and 1600°C. The solubility minimum of C and the maximum partial enthalpy of mixing of C in the ternary Fe-Ni-C system occurred at near the maximum short-range ordering composition of the binary Fe-Ni liquid solution. The extrema of the partial properties of C in the ternary Fe-Ni-C system were successfully reproduced with only one constant adjustable ternary parameter.",

author = "Min Paek and Junmo Jeon and Manas Paliwal and Arijit Biswas and Daniel Lindberg and Jong-Jin Pak",

year = "2021",

month = feb,

doi = "10.1007/s11837-020-04487-9",

language = "English",

volume = "73",

pages = "679--687",

journal = "JOM",

issn = "1047-4838",

publisher = "Springer",

number = "2",

}

TY - JOUR

T1 - Thermodynamic Assessment of Liquid Fe-Ni-C Alloy Using Modified Quasichemical Model

AU - Paek, Min

AU - Jeon, Junmo

AU - Paliwal, Manas

AU - Biswas, Arijit

AU - Lindberg, Daniel

AU - Pak, Jong-Jin

PY - 2021/2

Y1 - 2021/2

N2 - The liquid solution properties in the Fe-Ni and Fe-Ni-C systems have been thermodynamically assessed using the modified quasichemical model in the pair approximation. The asymmetry of the Fe-Ni and Fe-Ni-C alloy melts was verified by measuring the melting points of Fe-Ni binary alloys on the Ni-rich side, and the C solubility limit in Fe-Ni melt over the entire concentration range at 1500°C and 1600°C. The solubility minimum of C and the maximum partial enthalpy of mixing of C in the ternary Fe-Ni-C system occurred at near the maximum short-range ordering composition of the binary Fe-Ni liquid solution. The extrema of the partial properties of C in the ternary Fe-Ni-C system were successfully reproduced with only one constant adjustable ternary parameter.

AB - The liquid solution properties in the Fe-Ni and Fe-Ni-C systems have been thermodynamically assessed using the modified quasichemical model in the pair approximation. The asymmetry of the Fe-Ni and Fe-Ni-C alloy melts was verified by measuring the melting points of Fe-Ni binary alloys on the Ni-rich side, and the C solubility limit in Fe-Ni melt over the entire concentration range at 1500°C and 1600°C. The solubility minimum of C and the maximum partial enthalpy of mixing of C in the ternary Fe-Ni-C system occurred at near the maximum short-range ordering composition of the binary Fe-Ni liquid solution. The extrema of the partial properties of C in the ternary Fe-Ni-C system were successfully reproduced with only one constant adjustable ternary parameter.

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U2 - 10.1007/s11837-020-04487-9

DO - 10.1007/s11837-020-04487-9

M3 - Article

SN - 1047-4838

VL - 73

SP - 679

EP - 687

JO - JOM

JF - JOM

IS - 2

ER -

Thermodynamic Assessment of Liquid Fe-Ni-C Alloy Using Modified Quasichemical Model

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