Switching supramolecular polymeric materials with multiple length scales

Tutkimustuotos: Lehtiartikkelivertaisarvioitu

Standard

Switching supramolecular polymeric materials with multiple length scales. / Ruokolainen, J.; Mäkinen, R.; Torkkeli, M.; Mäkelä, T.; Serimaa, R.; ten Brinke, G.; Ikkala, O.

julkaisussa: Science, Vuosikerta 280, Nro 5363, 24.04.1998, s. 557-560.

Tutkimustuotos: Lehtiartikkelivertaisarvioitu

Harvard

Ruokolainen, J, Mäkinen, R, Torkkeli, M, Mäkelä, T, Serimaa, R, ten Brinke, G & Ikkala, O 1998, 'Switching supramolecular polymeric materials with multiple length scales', Science, Vuosikerta. 280, Nro 5363, Sivut 557-560. https://doi.org/10.1126/science.280.5363.557

APA

Ruokolainen, J., Mäkinen, R., Torkkeli, M., Mäkelä, T., Serimaa, R., ten Brinke, G., & Ikkala, O. (1998). Switching supramolecular polymeric materials with multiple length scales. Science, 280(5363), 557-560. https://doi.org/10.1126/science.280.5363.557

Vancouver

Ruokolainen J, Mäkinen R, Torkkeli M, Mäkelä T, Serimaa R, ten Brinke G et al. Switching supramolecular polymeric materials with multiple length scales. Science. 1998 huhti 24;280(5363):557-560. https://doi.org/10.1126/science.280.5363.557

Author

Ruokolainen, J. ; Mäkinen, R. ; Torkkeli, M. ; Mäkelä, T. ; Serimaa, R. ; ten Brinke, G. ; Ikkala, O. / Switching supramolecular polymeric materials with multiple length scales. Julkaisussa: Science. 1998 ; Vuosikerta 280, Nro 5363. Sivut 557-560.

Bibtex - Lataa

@article{1fd3b2693cd14521ae4861af4093388d,
title = "Switching supramolecular polymeric materials with multiple length scales",
abstract = "It was demonstrated that polymeric supramolecular nanostructures with several length scales allow straightforward tailoring of hierarchical order- disorder and order-order transitions and the concurrent switching of functional properties. Poly(4-vinyl pyridine) (P4VP) was stoichiometrically protonated with methane sulfonic acid (MSA) to form P4VP(MSA)1.0, which was then hydrogen-bonded to pentadecylphenol. Microphase separation, re- entrant closed-loop macrophase separation, and high-temperature macrophase separation were observed. When MSA and pentadecylphenol were complexed to the P4VP block of a microphase-separated diblock copolymer poly[styrene-block- (4-vinyl pyridine)], self-organized structures-in-structures were obtained whose hierarchical phase transitions can be controlled systematically. This microstructural control on two different length scales (in the present case, at 48 and 350 angstroms) was then used to introduce temperature-dependent transition in electrical conductivity.",
author = "J. Ruokolainen and R. M{\"a}kinen and M. Torkkeli and T. M{\"a}kel{\"a} and R. Serimaa and {ten Brinke}, G. and O. Ikkala",
year = "1998",
month = "4",
day = "24",
doi = "10.1126/science.280.5363.557",
language = "English",
volume = "280",
pages = "557--560",
journal = "Science",
issn = "0036-8075",
number = "5363",

}

RIS - Lataa

TY - JOUR

T1 - Switching supramolecular polymeric materials with multiple length scales

AU - Ruokolainen, J.

AU - Mäkinen, R.

AU - Torkkeli, M.

AU - Mäkelä, T.

AU - Serimaa, R.

AU - ten Brinke, G.

AU - Ikkala, O.

PY - 1998/4/24

Y1 - 1998/4/24

N2 - It was demonstrated that polymeric supramolecular nanostructures with several length scales allow straightforward tailoring of hierarchical order- disorder and order-order transitions and the concurrent switching of functional properties. Poly(4-vinyl pyridine) (P4VP) was stoichiometrically protonated with methane sulfonic acid (MSA) to form P4VP(MSA)1.0, which was then hydrogen-bonded to pentadecylphenol. Microphase separation, re- entrant closed-loop macrophase separation, and high-temperature macrophase separation were observed. When MSA and pentadecylphenol were complexed to the P4VP block of a microphase-separated diblock copolymer poly[styrene-block- (4-vinyl pyridine)], self-organized structures-in-structures were obtained whose hierarchical phase transitions can be controlled systematically. This microstructural control on two different length scales (in the present case, at 48 and 350 angstroms) was then used to introduce temperature-dependent transition in electrical conductivity.

AB - It was demonstrated that polymeric supramolecular nanostructures with several length scales allow straightforward tailoring of hierarchical order- disorder and order-order transitions and the concurrent switching of functional properties. Poly(4-vinyl pyridine) (P4VP) was stoichiometrically protonated with methane sulfonic acid (MSA) to form P4VP(MSA)1.0, which was then hydrogen-bonded to pentadecylphenol. Microphase separation, re- entrant closed-loop macrophase separation, and high-temperature macrophase separation were observed. When MSA and pentadecylphenol were complexed to the P4VP block of a microphase-separated diblock copolymer poly[styrene-block- (4-vinyl pyridine)], self-organized structures-in-structures were obtained whose hierarchical phase transitions can be controlled systematically. This microstructural control on two different length scales (in the present case, at 48 and 350 angstroms) was then used to introduce temperature-dependent transition in electrical conductivity.

UR - http://www.scopus.com/inward/record.url?scp=2642706704&partnerID=8YFLogxK

U2 - 10.1126/science.280.5363.557

DO - 10.1126/science.280.5363.557

M3 - Article

VL - 280

SP - 557

EP - 560

JO - Science

JF - Science

SN - 0036-8075

IS - 5363

ER -

ID: 4704650