Simultaneous endo and exo Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

Anniina Kiesilä; Lauri Kivijärvi; Ngong Kodiah Beyeh; Jani O. Moilanen; Michael Groessl; Tatiana Rothe; Sven Götz; Filip Topić; Kari Rissanen; Arne Lützen; Elina Kalenius

doi:10.1002/anie.201704054

Simultaneous endo and exo Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

Anniina Kiesilä, Lauri Kivijärvi, Ngong Kodiah Beyeh, Jani O. Moilanen, Michael Groessl, Tatiana Rothe, Sven Götz, Filip Topić, Kari Rissanen, Arne Lützen^*, Elina Kalenius

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Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

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Abstrakti

The formation of complexes between hexafluorophosphate (PF₆ ^-) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (¹H, ¹⁹F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF₆ ^- anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.

Alkuperäiskieli	Englanti
Sivut	10942–10946
Julkaisu	Angewandte Chemie
Vuosikerta	56
Numero	36
DOI - pysyväislinkit	https://doi.org/10.1002/anie.201704054
Tila	Julkaistu - 2017
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.1002/anie.201704054

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Link to publication in Scopus

CCDC 1543476: Experimental Crystal Structure Determination
Beyeh, N. (Creator), Götz, S. (Contributor), Groessl, M. (Contributor), Kalenius, E. (Contributor), Kiesilä, A. (Contributor), Kivijärvi, L. (Contributor), Lützen, A. (Contributor), Moilanen, J. O. (Contributor), Rissanen, K. (Contributor), Rothe, T. (Contributor) & Topić, F. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2017
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1nt3k4, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1nt3k4&sid=DataCite
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@article{2fcaf369e27a470cb4036ee77278e6f5,

title = "Simultaneous endo and exo Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests",

abstract = "The formation of complexes between hexafluorophosphate (PF6 -) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1H, 19F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6 - anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.",

keywords = "Anion binding, Ion mobility mass spectrometry, Molecular recognition, Pyridine[4]arenes, Resorcinarenes",

author = "Anniina Kiesil{\"a} and Lauri Kivij{\"a}rvi and Beyeh, {Ngong Kodiah} and Moilanen, {Jani O.} and Michael Groessl and Tatiana Rothe and Sven G{\"o}tz and Filip Topi{\'c} and Kari Rissanen and Arne L{\"u}tzen and Elina Kalenius",

year = "2017",

doi = "10.1002/anie.201704054",

language = "English",

volume = "56",

pages = "10942–10946",

journal = "Angewandte Chemie",

issn = "1433-7851",

publisher = "Wiley-VCH Verlag",

number = "36",

}

TY - JOUR

T1 - Simultaneous endo and exo Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

AU - Kiesilä, Anniina

AU - Kivijärvi, Lauri

AU - Beyeh, Ngong Kodiah

AU - Moilanen, Jani O.

AU - Groessl, Michael

AU - Rothe, Tatiana

AU - Götz, Sven

AU - Topić, Filip

AU - Rissanen, Kari

AU - Lützen, Arne

AU - Kalenius, Elina

PY - 2017

Y1 - 2017

N2 - The formation of complexes between hexafluorophosphate (PF6 -) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1H, 19F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6 - anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.

AB - The formation of complexes between hexafluorophosphate (PF6 -) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1H, 19F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6 - anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.

KW - Anion binding

KW - Ion mobility mass spectrometry

KW - Molecular recognition

KW - Pyridine[4]arenes

KW - Resorcinarenes

UR - http://www.scopus.com/inward/record.url?scp=85026738573&partnerID=8YFLogxK

U2 - 10.1002/anie.201704054

DO - 10.1002/anie.201704054

M3 - Article

AN - SCOPUS:85026738573

SN - 1433-7851

VL - 56

SP - 10942

EP - 10946

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 36

ER -

Simultaneous endo and exo Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

Abstrakti

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Tietoaineistot

CCDC 1543476: Experimental Crystal Structure Determination

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