Self-Sufficient Formaldehyde-to-Methanol Conversion by Organometallic Formaldehyde Dismutase Mimic

Dominic van der Waals, Leo E. Heim, Simona Vallazza, Christian Gedig, Jan Deska, Martin H. G. Prechtl

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

7 Sitaatiot (Scopus)
106 Lataukset (Pure)

Abstrakti

The catalytic networks of methylotrophic organisms, featuring redox enzymes for the activation of one-carbon moieties, can serve as great inspiration in the development of novel homogeneously catalyzed pathways for the interconversion of C1 molecules at ambient conditions. An imidazolium-tagged arene–ruthenium complex was identified as an effective functional mimic of the bacterial formaldehyde dismutase, which provides a new and highly selective route for the conversion of formaldehyde to methanol in absence of any external reducing agents. Moreover, secondary amines are reductively methylated by the organometallic dismutase mimic in a redox self-sufficient manner with formaldehyde acting both as carbon source and reducing agent.
AlkuperäiskieliEnglanti
Sivut11568-11573
Sivumäärä6
JulkaisuCHEMISTRY: A EUROPEAN JOURNAL
Vuosikerta22
Numero33
DOI - pysyväislinkit
TilaJulkaistu - 6 heinäkuuta 2016
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

Sormenjälki Sukella tutkimusaiheisiin 'Self-Sufficient Formaldehyde-to-Methanol Conversion by Organometallic Formaldehyde Dismutase Mimic'. Ne muodostavat yhdessä ainutlaatuisen sormenjäljen.

  • Siteeraa tätä