Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS2 catalyst

Yiming Ma; Yushuai Sang; Kai Wu; Qingfeng Liu; Hong Chen; Yongdan Li

doi:10.1016/j.cattod.2022.05.010

Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS₂ catalyst

Yiming Ma, Yushuai Sang, Kai Wu, Qingfeng Liu, Hong Chen, Yongdan Li

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

4 Sitaatiot (Scopus)

62 Lataukset (Pure)

Abstrakti

Low selectivity and complex product distribution are the main challenges for the utilization of lignin. Herein, the selective production of 2-(tert-butyl)-3-methylphenol (TBC), an antioxidant in the polymer industry, from depolymerization of enzymatic hydrolysis lignin (EHL) on a hydrothermally synthesized MoS₂ catalyst is studied. The total aromatic monomer yield is 124.1mg/g EHL and the selectivity of TBC is up to 40.3wt% in methanol at 280oC under 2MPa H2 for 6h. The FT-IR analysis of products reveals that MoS2 has a high activity for demethylation, dehydroxylation and alkylation, and the dimer conversions reveal that C-O and C-C bonds in EHL are broken with MoS2. The guaiacol and its derivants are identified as the intermediate for formation of TBC in EHL depolymerizaiton according to the effect of time on product distribution and monomer converison.

Alkuperäiskieli	Englanti
Sivut	194-203
Sivumäärä	10
Julkaisu	Catalysis Today
Vuosikerta	408
Varhainen verkossa julkaisun päivämäärä	12 toukok. 2022
DOI - pysyväislinkit	https://doi.org/10.1016/j.cattod.2022.05.010
Tila	Julkaistu - 15 tammik. 2023
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Pääsy asiakirjaan

10.1016/j.cattod.2022.05.010Lisenssi: CC BY-NC-ND

CHEM_Ma_et_al_Selective_Production_2022_Catalysis_TodayFinal published version, 6,84 MBLisenssi: CC BY-NC-ND

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Linkki julkaisuun Scopuksessa

EHLCATHOL: Chemical transformation of enzymatic hydrolysis lignin (EHL) with catalytic solvolysis to fuel commodities under mild conditions
Li, Y. (Vastuullinen tutkija), Long, J. (Projektin jäsen), Kaur, P. (Projektin jäsen), Saravanan Kasipandi, S. (Projektin jäsen), Li, X. (Projektin jäsen), Sang, Y. (Projektin jäsen), Li, G. (Projektin jäsen), Yong, X. (Projektin jäsen), Singh, A. (Projektin jäsen), Arkış, N. (Projektin jäsen) & Wang, J. (Projektin jäsen)
01/11/2020 → 31/10/2024
Projekti: EU: Framework programmes funding

Siteeraa tätä

@article{8dda993b4ebb4d6495b90c947b551428,

title = "Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS2 catalyst",

abstract = "Low selectivity and complex product distribution are the main challenges for the utilization of lignin. Herein, the selective production of 2-(tert-butyl)-3-methylphenol (TBC), an antioxidant in the polymer industry, from depolymerization of enzymatic hydrolysis lignin (EHL) on a hydrothermally synthesized MoS2 catalyst is studied. The total aromatic monomer yield is 124.1mg/g EHL and the selectivity of TBC is up to 40.3wt% in methanol at 280oC under 2MPa H2 for 6h. The FT-IR analysis of products reveals that MoS2 has a high activity for demethylation, dehydroxylation and alkylation, and the dimer conversions reveal that C-O and C-C bonds in EHL are broken with MoS2. The guaiacol and its derivants are identified as the intermediate for formation of TBC in EHL depolymerizaiton according to the effect of time on product distribution and monomer converison.",

keywords = "Depolymerization, Phenolic monomer, Lignin, MoS",

author = "Yiming Ma and Yushuai Sang and Kai Wu and Qingfeng Liu and Hong Chen and Yongdan Li",

note = "| openaire: EC/H2020/101006744/EU//EHLCATHOL This work is supported by the National Natural Science Foundation of China (21808163). This project has received funding from the European Union{\textquoteright}s Horizon 2020 research and innovation programme under grant agreement No 101006744. The content presented in this document represents the views of the authors, and the European Commission has no liability in respect of the content.",

year = "2023",

month = jan,

day = "15",

doi = "10.1016/j.cattod.2022.05.010",

language = "English",

volume = "408",

pages = "194--203",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier Science B.V.",

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T1 - Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS2 catalyst

AU - Ma, Yiming

AU - Sang, Yushuai

AU - Wu, Kai

AU - Liu, Qingfeng

AU - Chen, Hong

AU - Li, Yongdan

N1 - | openaire: EC/H2020/101006744/EU//EHLCATHOL This work is supported by the National Natural Science Foundation of China (21808163). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 101006744. The content presented in this document represents the views of the authors, and the European Commission has no liability in respect of the content.

PY - 2023/1/15

Y1 - 2023/1/15

N2 - Low selectivity and complex product distribution are the main challenges for the utilization of lignin. Herein, the selective production of 2-(tert-butyl)-3-methylphenol (TBC), an antioxidant in the polymer industry, from depolymerization of enzymatic hydrolysis lignin (EHL) on a hydrothermally synthesized MoS2 catalyst is studied. The total aromatic monomer yield is 124.1mg/g EHL and the selectivity of TBC is up to 40.3wt% in methanol at 280oC under 2MPa H2 for 6h. The FT-IR analysis of products reveals that MoS2 has a high activity for demethylation, dehydroxylation and alkylation, and the dimer conversions reveal that C-O and C-C bonds in EHL are broken with MoS2. The guaiacol and its derivants are identified as the intermediate for formation of TBC in EHL depolymerizaiton according to the effect of time on product distribution and monomer converison.

AB - Low selectivity and complex product distribution are the main challenges for the utilization of lignin. Herein, the selective production of 2-(tert-butyl)-3-methylphenol (TBC), an antioxidant in the polymer industry, from depolymerization of enzymatic hydrolysis lignin (EHL) on a hydrothermally synthesized MoS2 catalyst is studied. The total aromatic monomer yield is 124.1mg/g EHL and the selectivity of TBC is up to 40.3wt% in methanol at 280oC under 2MPa H2 for 6h. The FT-IR analysis of products reveals that MoS2 has a high activity for demethylation, dehydroxylation and alkylation, and the dimer conversions reveal that C-O and C-C bonds in EHL are broken with MoS2. The guaiacol and its derivants are identified as the intermediate for formation of TBC in EHL depolymerizaiton according to the effect of time on product distribution and monomer converison.

KW - Depolymerization

KW - Phenolic monomer

KW - Lignin

KW - MoS

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U2 - 10.1016/j.cattod.2022.05.010

DO - 10.1016/j.cattod.2022.05.010

M3 - Article

SN - 0920-5861

VL - 408

SP - 194

EP - 203

JO - Catalysis Today

JF - Catalysis Today

ER -

Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS2 catalyst

Abstrakti

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

EHLCATHOL: Chemical transformation of enzymatic hydrolysis lignin (EHL) with catalytic solvolysis to fuel commodities under mild conditions

Siteeraa tätä

Selective production of 2-(tert-butyl)-3-methylphenol from depolymerization of enzymatic hydrolysis lignin with MoS₂ catalyst