Revealing pore size distribution in cellulose and lignin-cellulose man-made fibers – effect of draw ratio and lignin content

Jenny Bengtsson*, Erica Johnsson, Hanna Ulmefors, Tobias Köhnke, Thaddeus Maloney

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

1 Sitaatiot (Scopus)
40 Lataukset (Pure)

Abstrakti

There are limited methods available for measurement of the porosity of cellulose fibers, even more so for obtaining a pore size distribution. Conventional pore analysis methods require dry samples, with intact pores. However, pores in cellulose fibers collapse when dried from water and thus present a challenge for sample analysis. Furthermore, the pore collapse is partially irreversible which should be accounted for in the analysis. In this study, analysis of pore structure was carried out in the wet state with thermoporometry and also for critical point dried samples, analyzed with N2 sorption. This study determines the effect of fiber lignin content and certain spinning parameters on the pore size distribution of spun fibers before and after drying. It could also be concluded that solvent exchange, drying from a non-polar solvent will result in an altered pore size distribution, with a total pore volume greater than if dried from water, however not representative of the never-dried state. It is concluded that thermoporometry together with the water retention value (WRV) measurement is a powerful combination to acquire insights to the pore size distribution of spun fiber.

AlkuperäiskieliEnglanti
Sivut7003–7013
JulkaisuCellulose
Vuosikerta31
Numero11
Varhainen verkossa julkaisun päivämäärä14 kesäk. 2024
DOI - pysyväislinkit
TilaJulkaistu - heinäk. 2024
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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