Redefining polyamide property profiles via renewable long-chain aliphatic segments: Towards impact resistance and low water absorption

Tutkimustuotos: Lehtiartikkelivertaisarvioitu

Tutkijat

Organisaatiot

Kuvaus

A series of renewable, long-chain, fatty acid-derived polyamides (PA) ranging from PA 6,14 to PA 6,18 were synthesized via polycondensation, yielding very high molecular weights and a remarkable property profile distinct from short-chain commercial grades. Most notably, synthesized polyamides exhibited good impact resistance, excellent stiffness-to-toughness balance and very low water absorption yet high oxygen and water vapour permeability; with this property profile being exemplified by PA 6,18. The increased repeating unit length and reduced number of amide linkages able to participate in interchain hydrogen bonding imparted a strong influence on material properties. The data highlights the benefits and technical advantages of utilising long-chain polyamides, while also significantly expanding the repertoire, knowledge and property profile of the long-chain aliphatic polyamide family, and providing a basis for further development of polyamides from renewable sources.

Yksityiskohdat

AlkuperäiskieliEnglanti
Sivut16-25
Sivumäärä10
JulkaisuEuropean Polymer Journal
Vuosikerta109
TilaJulkaistu - 1 joulukuuta 2018
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

ID: 27963162