Reaction kinetics of strong nucleophiles with a dimeric non-phenolic lignin model compound with α-carbonyl functionality (adleron) in aqueous alkali solution

Olesya Fearon*, Susanna Kuitunen, Tapani Vuorinen

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

Abstrakti

The degradation kinetics of a non-phenolic lignin model compound with α-carbonyl functionality (adlerone) has been studied by varying temperature and concentrations of sodium hydroxide, sodium hydrogen sulfide, and sodium sulfite. The kinetics of adlerone degradation and formation of its reaction products were monitored by UV-Vis spectroscopy and their structures were analyzed by GC/MS. The two step degradation of adlerone was studied in two separate experimental setups. In the first alkali catalyzed step, adlerone is converted to a β-elimination product that reacts further in the second step with hydrogen sulfide or sulfite ion. The Arrhenius kinetic parameters were derived by the KinFit software. The activation energy for the 1st step was 69.1 kJ mol-1, and for the 2nd step with sulfide 42.4 kJ mol-1 and with sulfite ion 35.8 kJ mol-1. The reaction mechanisms presented are in line with those published earlier: β-ether bonds of structures having α-carbonyl functionality do not cleave under soda pulping conditions, whereas in kraft and sulfite pulping the cleavage of β-ether bonds proceeds via nucleophile attack and addition. The combination of hydroxyl and sulfite ions gives the fastest cleavage of β-ether bonds in non-phenolic lignin structures with the α-carbonyl functionality.

AlkuperäiskieliEnglanti
Sivut811-818
Sivumäärä8
JulkaisuHolzforschung
Vuosikerta70
Numero9
DOI - pysyväislinkit
TilaJulkaistu - 1 syyskuuta 2016
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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