Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence

Igor O. Koshevoy; Chia-Li Lin; Antti J. Karttunen; Matti Haukka; Chun-Wei Shih; Pi-Tai Chou; Sergey P. Tunik; Tapani A. Pakkanen

doi:10.1039/c1cc11352f

Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence

Igor O. Koshevoy^*, Chia-Li Lin, Antti J. Karttunen, Matti Haukka, Chun-Wei Shih, Pi-Tai Chou, Sergey P. Tunik, Tapani A. Pakkanen

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Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

Abstrakti

The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.

Alkuperäiskieli	Englanti
Sivut	5533-5535
Sivumäärä	3
Julkaisu	Chemical Communications
Vuosikerta	47
Numero	19
DOI - pysyväislinkit	https://doi.org/10.1039/c1cc11352f
Tila	Julkaistu - 2011
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Pääsy asiakirjaan

10.1039/c1cc11352f

Siteeraa tätä

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title = "Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence",

abstract = "The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.",

keywords = "COMPLEXES, AUROPHILICITY",

author = "Koshevoy, {Igor O.} and Chia-Li Lin and Karttunen, {Antti J.} and Matti Haukka and Chun-Wei Shih and Pi-Tai Chou and Tunik, {Sergey P.} and Pakkanen, {Tapani A.}",

year = "2011",

doi = "10.1039/c1cc11352f",

language = "English",

volume = "47",

pages = "5533--5535",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence

AU - Koshevoy, Igor O.

AU - Lin, Chia-Li

AU - Karttunen, Antti J.

AU - Haukka, Matti

AU - Shih, Chun-Wei

AU - Chou, Pi-Tai

AU - Tunik, Sergey P.

AU - Pakkanen, Tapani A.

PY - 2011

Y1 - 2011

N2 - The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.

AB - The unprecedented, purely gold(I) alkynyl-diphosphine clusters 1-3 demonstrate intense room-temperature phosphorescence with maximum quantum efficiency of 92% in solution (3) and 86% in solid (2) and thermally dependent emission in the crystalline form, attributed to the crystal lattice arrangement.

KW - COMPLEXES

KW - AUROPHILICITY

U2 - 10.1039/c1cc11352f

DO - 10.1039/c1cc11352f

M3 - Article

SN - 1359-7345

VL - 47

SP - 5533

EP - 5535

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Octanuclear gold(I) alkynyl-diphosphine clusters showing thermochromic luminescence

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