NIR-absorbing transition metal complexes with redox-active ligands

Esko Salojärvi; Anssi Peuronen; Hannu Huhtinen; Leonid S. Vlasenko; Janne Halme; Pyry Mäkinen; Mika Lastusaari; Ari Lehtonen

doi:10.1016/j.inoche.2019.107711

NIR-absorbing transition metal complexes with redox-active ligands

Esko Salojärvi, Anssi Peuronen, Hannu Huhtinen, Leonid S. Vlasenko, Janne Halme, Pyry Mäkinen, Mika Lastusaari, Ari Lehtonen^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

5 Sitaatiot (Scopus)

49 Lataukset (Pure)

Abstrakti

Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region.

Alkuperäiskieli	Englanti
Artikkeli	107711
Sivut	1-4
Sivumäärä	4
Julkaisu	INORGANIC CHEMISTRY COMMUNICATIONS
Vuosikerta	112
DOI - pysyväislinkit	https://doi.org/10.1016/j.inoche.2019.107711
Tila	Julkaistu - 1 helmik. 2020
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.1016/j.inoche.2019.107711

SCI_Salojärvi_et.al_NIR-absorbing_transition_metalAccepted author manuscript, 0,99 MBLisenssi: CC BY-NC-ND

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@article{3d12acc644904db89dce74dc69903338,

title = "NIR-absorbing transition metal complexes with redox-active ligands",

abstract = "Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region.",

keywords = "Metal complexes, Near-IR absorption, Non-innocent ligands, Redox-active ligands",

author = "Esko Saloj{\"a}rvi and Anssi Peuronen and Hannu Huhtinen and Vlasenko, {Leonid S.} and Janne Halme and Pyry M{\"a}kinen and Mika Lastusaari and Ari Lehtonen",

year = "2020",

month = feb,

day = "1",

doi = "10.1016/j.inoche.2019.107711",

language = "English",

volume = "112",

pages = "1--4",

journal = "INORGANIC CHEMISTRY COMMUNICATIONS",

issn = "1387-7003",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - NIR-absorbing transition metal complexes with redox-active ligands

AU - Salojärvi, Esko

AU - Peuronen, Anssi

AU - Huhtinen, Hannu

AU - Vlasenko, Leonid S.

AU - Halme, Janne

AU - Mäkinen, Pyry

AU - Lastusaari, Mika

AU - Lehtonen, Ari

PY - 2020/2/1

Y1 - 2020/2/1

N2 - Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region.

AB - Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region.

KW - Metal complexes

KW - Near-IR absorption

KW - Non-innocent ligands

KW - Redox-active ligands

UR - http://www.scopus.com/inward/record.url?scp=85075983143&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2019.107711

DO - 10.1016/j.inoche.2019.107711

M3 - Article

AN - SCOPUS:85075983143

SN - 1387-7003

VL - 112

SP - 1

EP - 4

JO - INORGANIC CHEMISTRY COMMUNICATIONS

JF - INORGANIC CHEMISTRY COMMUNICATIONS

M1 - 107711

ER -

NIR-absorbing transition metal complexes with redox-active ligands

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