New s-Block Metal Pyridinedicarboxylate Network Structures through Gas-Phase Thin-Film Synthesis

Jenna Penttinen, Mikko Nisula, Maarit Karppinen*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

3 Sitaatiot (Scopus)

Abstrakti

The combined atomic and molecular layer deposition (ALD/MLD) technique offers a unique way to build—both known and previously unknown—crystalline coordination polymer materials directly from gaseous precursors in a high-quality thin-film form. Here, we demonstrate the ALD/MLD of crystalline Li-, Na-, and K-based 3,5-pyridinedicarboxylate (3,5-PDC) thin films; the Li2-3,5-PDC films are of the known Li-ULMOF-4 crystal structure whereas the other as-deposited crystalline films possess structures not previously reported. Another exciting possibility offered by ALD/MLD is the deposition of well-defined but amorphous metal–organic thin films, such as our Mg-, Ca-, Sr-, and Ba-based 3,5-PDC films, which can then be crystallized into water-containing structures through a post-deposition humidity treatment. All together, the new metal–organic structures realized in this study through ALD/MLD comprise a majority of the (anhydrous and water-containing) members of the s-block metal 3,5-pyridinedicarboxylate family.

AlkuperäiskieliEnglanti
JulkaisuChemistry - A European Journal
DOI - pysyväislinkit
TilaJulkaistu - 1 tammikuuta 2019
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

Sormenjälki Sukella tutkimusaiheisiin 'New s-Block Metal Pyridinedicarboxylate Network Structures through Gas-Phase Thin-Film Synthesis'. Ne muodostavat yhdessä ainutlaatuisen sormenjäljen.

  • Projektit

    Uusia hybridimateriaaleja ALD/MLD:n avulla: perusteista sovelluksiin

    Aleksandrova, I., Medina, E., Thomas, C., Karppinen, M., Haggren, A., Tiittanen, T., Penttinen, J., Ghazy, A., Mustonen, O., Khayyami, A., Revitzer, H., Sederholm, L. & Johansson, L.

    01/09/201631/08/2020

    Projekti: Academy of Finland: Other research funding

    Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa

    Lahtinen, K., Kallio, T. & Revitzer, H.

    01/04/201623/09/2019

    Projekti: Academy of Finland: Strategic research funding

    Laitteet

    OtaNano

    Anna Rissanen (Manager)

    Aalto-yliopisto

    Laitteistot/tilat: Facility

  • Siteeraa tätä