N-Alkyl ammonium resorcinarene polyiodides

Fangfang Pan; Ngong Kodiah Beyeh; Robin H A Ras; Kari Rissanen

doi:10.1039/c6ce01229a

N-Alkyl ammonium resorcinarene polyiodides

Fangfang Pan, Ngong Kodiah Beyeh^*, Robin H A Ras, Kari Rissanen

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

5 Sitaatiot (Scopus)

Abstrakti

Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I₂) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I^- further binds one or two I₂ molecules resulting in I₃ ^- or I₅ ^- species, respectively.

Alkuperäiskieli	Englanti
Sivut	5724-5727
Sivumäärä	4
Julkaisu	CrystEngComm
Vuosikerta	18
Numero	30
DOI - pysyväislinkit	https://doi.org/10.1039/c6ce01229a
Tila	Julkaistu - kesäk. 2016
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Pääsy asiakirjaan

10.1039/c6ce01229a

Muut tiedostot ja linkit

Link to publication in Scopus

CCDC 1481999: Experimental Crystal Structure Determination
Beyeh, N. (Contributor), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2016
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1lr4fx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4fx&sid=DataCite
Tietoaineisto: Dataset
CCDC 1481996: Experimental Crystal Structure Determination
Beyeh, N. (Creator), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2016
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1lr4bt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4bt&sid=DataCite
Tietoaineisto: Dataset
CCDC 1481997: Experimental Crystal Structure Determination
Beyeh, N. (Creator), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2016
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1lr4cv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4cv&sid=DataCite
Tietoaineisto: Dataset

Siteeraa tätä

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title = "N-Alkyl ammonium resorcinarene polyiodides",

abstract = "Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.",

author = "Fangfang Pan and Beyeh, {Ngong Kodiah} and Ras, {Robin H A} and Kari Rissanen",

year = "2016",

month = jun,

doi = "10.1039/c6ce01229a",

language = "English",

volume = "18",

pages = "5724--5727",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "30",

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TY - JOUR

T1 - N-Alkyl ammonium resorcinarene polyiodides

AU - Pan, Fangfang

AU - Beyeh, Ngong Kodiah

AU - Ras, Robin H A

AU - Rissanen, Kari

PY - 2016/6

Y1 - 2016/6

N2 - Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.

AB - Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84979896218&partnerID=8YFLogxK

U2 - 10.1039/c6ce01229a

DO - 10.1039/c6ce01229a

M3 - Article

AN - SCOPUS:84979896218

SN - 1466-8033

VL - 18

SP - 5724

EP - 5727

JO - CrystEngComm

JF - CrystEngComm

IS - 30

ER -

N-Alkyl ammonium resorcinarene polyiodides

Abstrakti

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Tietoaineistot

CCDC 1481999: Experimental Crystal Structure Determination

CCDC 1481996: Experimental Crystal Structure Determination

CCDC 1481997: Experimental Crystal Structure Determination

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