Multi-scale model for the structure of hybrid perovskites: Analysis of charge migration in disordered MAPbI3 structures

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

3 Sitaatiot (Scopus)
27 Lataukset (Pure)

Abstrakti

We have developed a multi-scale model for organic-inorganic hybrid perovskites (HPs) that applies quantum mechanical (QM) calculations of small HP supercell models to large coarse-grained structures. With a mixed quantum-classical hopping model, we have studied the effects of cation disorder on charge mobilities in HPs, which is a key feature to optimize their photovoltaic performance. Our multi-scale model parametrizes the interaction between neighboring methylammonium cations (MA+) in the prototypical HP material, methylammonium lead triiodide (CH3NH3PbI3, or MAPbI3). For the charge mobility analysis with our hopping model, we solved the QM site-to-site hopping probabilities analytically and computed the nearest-neighbor electronic coupling energies from the band structure of MAPbI3 with density-functional theory. We investigated the charge mobility in various MAPbI3 supercell models of ordered and disordered MA+ cations. Our results indicate a structure-dependent mobility, in the range of 50-66 cm2 V-1 s-1, with the highest observed in the ordered tetragonal phase.

AlkuperäiskieliEnglanti
Artikkeli103013
Sivut1-19
JulkaisuNew Journal of Physics
Vuosikerta20
Numero10
DOI - pysyväislinkit
TilaJulkaistu - 10 lokakuuta 2018
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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