Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

Thomas Straub; Martin Brunner; Ari M.P. Koskinen

doi:10.2174/1570178053399868

Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

Thomas Straub
, Martin Brunner
, Ari M.P. Koskinen

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

2 Sitaatiot (Scopus)

201 Lataukset (Pure)

Abstrakti

Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.

Alkuperäiskieli	Englanti
Sivut	74-76
Julkaisu	Letters in Organic Chemistry
Vuosikerta	2
DOI - pysyväislinkit	https://doi.org/10.2174/1570178053399868
Tila	Julkaistu - 2005
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Tutkimusalat

alkyne coupling
catalytic
cross-linking
unsaturated polyester

Pääsy asiakirjaan

10.2174/1570178053399868

Model_Studies_Towards_Alternative_Cross-Linking_ofAccepted author manuscript, 80,4 KB

Siteeraa tätä

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title = "Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters",

abstract = "Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.",

keywords = "alkyne coupling, catalytic, cross-linking, unsaturated polyester, alkyne coupling, catalytic, cross-linking, unsaturated polyester, alkyne coupling, catalytic, cross-linking, unsaturated polyester",

author = "Thomas Straub and Martin Brunner and Koskinen, \{Ari M.P.\}",

year = "2005",

doi = "10.2174/1570178053399868",

language = "English",

volume = "2",

pages = "74--76",

journal = "Letters in Organic Chemistry",

issn = "1875-6255",

publisher = "Bentham Science Publishers",

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TY - JOUR

T1 - Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

AU - Straub, Thomas

AU - Brunner, Martin

AU - Koskinen, Ari M.P.

PY - 2005

Y1 - 2005

N2 - Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.

AB - Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.

KW - alkyne coupling

KW - catalytic

KW - cross-linking

KW - unsaturated polyester

KW - alkyne coupling

KW - catalytic

KW - cross-linking

KW - unsaturated polyester

KW - alkyne coupling

KW - catalytic

KW - cross-linking

KW - unsaturated polyester

U2 - 10.2174/1570178053399868

DO - 10.2174/1570178053399868

M3 - Article

SN - 1875-6255

VL - 2

SP - 74

EP - 76

JO - Letters in Organic Chemistry

JF - Letters in Organic Chemistry

ER -

Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

Abstrakti

Tutkimusalat

Pääsy asiakirjaan

Sormenjälki

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