Microstructure evolution and mechanical properties of Ti-B-N coatings deposited by plasma-enhanced chemical vapor deposition

Jung Ho Shin, Kwang Soo Choi, Tie -gang Wang, Kwang Ho Kim*, Roman Nowak

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

13 Sitaatiot (Scopus)

Abstrakti

Ternary Ti-B-N coatings were synthesized on AISI 304 and Si wafer by plasma-enhanced chemical vapor deposition (PECVD) technique using a gaseous mixture of TiCl4, BCl3, H2, N2, and Ar. By virtue of X-ray diffraction analysis, X-ray photoelectron spectroscopy, scanning electron microscope, and high-resolution transmission electron microscope, the influences of B content on the microstructure and properties of Ti-B-N coatings were investigated systematically. The results indicated that the microstructure and mechanical properties of Ti-B-N coatings largely depend on the transformation from FCC-TiN phase to HCP-TiB2 phase. With increasing B content and decreasing N content in the coatings, the coating microstructure evolves gradually from FCC-TiN/a-BN to HCP-TiB2/a-BN via FCC-TiN+HCP-TiB2/a-BN. The highest microhardness of about 34 GPa is achieved, which corresponds to the nanocomposite Ti-63%B-N (mole fraction) coating consisting of the HCP-TiB2 nano-crystallites and amorphous BN phase. The lowest friction-coefficient was observed for the nanocomposite Ti-41%B-N (mole fraction) coating consisting of the FCC-TiN nanocrystallites and amorphous BN phase.

AlkuperäiskieliEnglanti
Sivuts722-s728
Sivumäärä7
JulkaisuTRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Vuosikerta22
NumeroSUPPL.3
DOI - pysyväislinkit
TilaJulkaistu - joulukuuta 2012
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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