TY - JOUR
T1 - Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)
AU - Schlapp-Hackl, Inge
AU - Hassenrueck, Christopher
AU - Wurst, Klaus
AU - Kopacka, Holger
AU - Mueller, Thomas
AU - Winter, Reiner F.
AU - Bildstein, Benno
PY - 2018/11
Y1 - 2018/11
N2 - The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.
AB - The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.
U2 - 10.1002/ejic.201800774
DO - 10.1002/ejic.201800774
M3 - Article
VL - 2018
SP - 4434
EP - 4441
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 40
ER -