Mechanism of Li-Ion Migration in the Superionic Conducting Open-Framework Structure Li6B18(Li3N)1-x(Li2O)x(0 ≤ x ≤ 1)

Robert J. Spranger, Holger Kirchhain, Tassilo M.F. Restle, Jasmin V. Dums, Antti J. Karttunen, Leo Van Wüllen*, Thomas F. Fässler*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

2 Sitaatiot (Scopus)

Abstrakti

Solid lithium-ion conductors are important components for all-solid-state batteries and the knowledge of the mechanism of Li diffusion is an important step in improving known materials and developing new materials. For the Li-ion conductor α-Li3N, the lithium diffusion process has been intensively investigated. We report here on the Li-ion diffusion in the open-framework structure Li6B18(Li3N)1-x(Li2O) in which Li3N and/or Li2O serve as a guest. Whereas vacancy formation for α-Li3N is not possible by forming a solid solution with Li2O, the solid solution of Li6B18(Li3N)1-x(Li2O)x exists over the whole composition range with an increasing number of Li vacancies with x and samples for x = 0, 0.25, 0.5, 0.75, and 1 are investigated. A variety of solid-state NMR approaches, including 7Li T1 relaxation NMR, temperature-dependent 6Li-magic angle spinning (MAS)-NMR, and 6Li-{7Li}-cross-polarization (CP)-MAS 2D-exchange NMR, and a detailed 7Li line shape analysis are combined with quantum chemical calculations of Li migration pathways to unravel the mechanism of Li diffusion in the open-framework structures Li6B18(Li3N)1-x(Li2O)x, hosting three different Li sites. The combined results indicate an anisotropic Li diffusion process, in which the motion along the crystallographic c-direction seems to be strongly hindered (Li2 ↔ Li3). On the other hand, the diffusion pathway in the ab-plane is characterized by a two-step motional process that combines Li1 ↔ Li2 and Li2 ↔ Li2 jumps with very low activation energies in the range of 30-40 kJ/mol for Li1 ↔ Li2 and 5-15 kJ/mol for Li2 ↔ Li2. Thus, lithium migration within the title compound bears strong similarities to the Li diffusion processes present in the well-known Li-ion conductor α-Li3N.

AlkuperäiskieliEnglanti
Sivut1622–1632
JulkaisuJournal of Physical Chemistry C
Vuosikerta127
Numero3
Varhainen verkossa julkaisun päivämäärä10 tammik. 2023
DOI - pysyväislinkit
TilaJulkaistu - 26 tammik. 2023
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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