Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)

Jan L. Wikaira; Raymond J. Butcher; Ulo Kersen; Mark M. Turnbull

doi:10.1080/00958972.2015.1116687

Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)

Jan L. Wikaira, Raymond J. Butcher, Ulo Kersen, Mark M. Turnbull^*

^*Tämän työn vastaava kirjoittaja

Kemian tekniikan ja metallurgian laitos

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

5 Sitaatiot (Scopus)

Abstrakti

Reaction of 4,4-bipiperidine (bipip) with copper(II) bromide in aqueous HBr yielded the salts (H(2)bipip)CuBr4H2O (2) and (H(2)bipip)(2)Cu2Br6 (3). Compound 2 crystallizes in the space group P2(1)/m and forms alternating layers of the H(2)bipip cations and CuBr4 anions with the water molecules located in the anionic layer. Compound 3 contains Cu(I) and crystallizes in the space group P2(1)/c and comprises stacks of H(2)bipip cations alternating with stacks of Cu2Br64- anions. Temperature-dependent magnetic measurements on 2 and its chloride analog, 1, show distinctly different behaviors supported by the two-halide superexchange pathway. The chloride compound (1) is best described as weakly interacting antiferromagnetic dimers (J similar to-13K), while the bromide compound (2) exhibits very weak ferromagnetic interactions best modeled as a uniform chain with J=2.45 (9)K (using the H=-J(AB)sigma SASB Hamiltonian).

[GRAPHICS]

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Alkuperäiskieli	Englanti
Sivut	57-71
Sivumäärä	15
Julkaisu	Journal of Coordination Chemistry
Vuosikerta	69
Numero	1
DOI - pysyväislinkit	https://doi.org/10.1080/00958972.2015.1116687
Tila	Julkaistu - 2016
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Pääsy asiakirjaan

10.1080/00958972.2015.1116687

CCDC 1400760: Experimental Crystal Structure Determination
Butcher, R. J. (Contributor), Kersen, U. (Creator), Turnbull, M. M. (Contributor) & Wikaira, J. L. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2016
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1j0lty, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1j0lty&sid=DataCite
Tietoaineisto: Dataset
CCDC 1400759: Experimental Crystal Structure Determination
Butcher, R. J. (Contributor), Kersen, U. (Creator), Turnbull, M. M. (Contributor) & Wikaira, J. L. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2016
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1j0lsx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1j0lsx&sid=DataCite
Tietoaineisto: Dataset

Siteeraa tätä

@article{58b7671a977c436699a9d5f286627478,

title = "Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)",

abstract = "Reaction of 4,4-bipiperidine (bipip) with copper(II) bromide in aqueous HBr yielded the salts (H(2)bipip)CuBr4H2O (2) and (H(2)bipip)(2)Cu2Br6 (3). Compound 2 crystallizes in the space group P2(1)/m and forms alternating layers of the H(2)bipip cations and CuBr4 anions with the water molecules located in the anionic layer. Compound 3 contains Cu(I) and crystallizes in the space group P2(1)/c and comprises stacks of H(2)bipip cations alternating with stacks of Cu2Br64- anions. Temperature-dependent magnetic measurements on 2 and its chloride analog, 1, show distinctly different behaviors supported by the two-halide superexchange pathway. The chloride compound (1) is best described as weakly interacting antiferromagnetic dimers (J similar to-13K), while the bromide compound (2) exhibits very weak ferromagnetic interactions best modeled as a uniform chain with J=2.45 (9)K (using the H=-J(AB)sigma SASB Hamiltonian).[GRAPHICS].",

keywords = "Tetrahalocuprate(II), magnetism, crystal structure, Cu(I) Halide, 4, 4-Bipiperidine, MOLECULAR MAGNETISM, COPPER(II), HALIDE, COMPLEXES, EXCHANGE, BEHAVIOR, BROMIDE, LADDER, CHAIN, SALTS",

author = "Wikaira, {Jan L.} and Butcher, {Raymond J.} and Ulo Kersen and Turnbull, {Mark M.}",

year = "2016",

doi = "10.1080/00958972.2015.1116687",

language = "English",

volume = "69",

pages = "57--71",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor & Francis",

number = "1",

}

Wikaira, JL, Butcher, RJ, Kersen, U & Turnbull, MM 2016, 'Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)', Journal of Coordination Chemistry, Vuosikerta 69, Nro 1, Sivut 57-71. https://doi.org/10.1080/00958972.2015.1116687

Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I). / Wikaira, Jan L.; Butcher, Raymond J.; Kersen, Ulo et al.
julkaisussa: Journal of Coordination Chemistry, Vuosikerta 69, Nro 1, 2016, s. 57-71.

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

TY - JOUR

T1 - Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)

AU - Wikaira, Jan L.

AU - Butcher, Raymond J.

AU - Kersen, Ulo

AU - Turnbull, Mark M.

PY - 2016

Y1 - 2016

N2 - Reaction of 4,4-bipiperidine (bipip) with copper(II) bromide in aqueous HBr yielded the salts (H(2)bipip)CuBr4H2O (2) and (H(2)bipip)(2)Cu2Br6 (3). Compound 2 crystallizes in the space group P2(1)/m and forms alternating layers of the H(2)bipip cations and CuBr4 anions with the water molecules located in the anionic layer. Compound 3 contains Cu(I) and crystallizes in the space group P2(1)/c and comprises stacks of H(2)bipip cations alternating with stacks of Cu2Br64- anions. Temperature-dependent magnetic measurements on 2 and its chloride analog, 1, show distinctly different behaviors supported by the two-halide superexchange pathway. The chloride compound (1) is best described as weakly interacting antiferromagnetic dimers (J similar to-13K), while the bromide compound (2) exhibits very weak ferromagnetic interactions best modeled as a uniform chain with J=2.45 (9)K (using the H=-J(AB)sigma SASB Hamiltonian).[GRAPHICS].

AB - Reaction of 4,4-bipiperidine (bipip) with copper(II) bromide in aqueous HBr yielded the salts (H(2)bipip)CuBr4H2O (2) and (H(2)bipip)(2)Cu2Br6 (3). Compound 2 crystallizes in the space group P2(1)/m and forms alternating layers of the H(2)bipip cations and CuBr4 anions with the water molecules located in the anionic layer. Compound 3 contains Cu(I) and crystallizes in the space group P2(1)/c and comprises stacks of H(2)bipip cations alternating with stacks of Cu2Br64- anions. Temperature-dependent magnetic measurements on 2 and its chloride analog, 1, show distinctly different behaviors supported by the two-halide superexchange pathway. The chloride compound (1) is best described as weakly interacting antiferromagnetic dimers (J similar to-13K), while the bromide compound (2) exhibits very weak ferromagnetic interactions best modeled as a uniform chain with J=2.45 (9)K (using the H=-J(AB)sigma SASB Hamiltonian).[GRAPHICS].

KW - Tetrahalocuprate(II)

KW - magnetism

KW - crystal structure

KW - Cu(I) Halide

KW - 4

KW - 4-Bipiperidine

KW - MOLECULAR MAGNETISM

KW - COPPER(II)

KW - HALIDE

KW - COMPLEXES

KW - EXCHANGE

KW - BEHAVIOR

KW - BROMIDE

KW - LADDER

KW - CHAIN

KW - SALTS

U2 - 10.1080/00958972.2015.1116687

DO - 10.1080/00958972.2015.1116687

M3 - Article

SN - 0095-8972

VL - 69

SP - 57

EP - 71

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 1

ER -

Magnetic properties of 4,4-bipiperidinediium tetrahalocuprates: crystal structures of 4,4-bipiperidinediium tetrabromocuprate(II) monohydrate and bis(4,4-bipiperidinediium) hexabromodicuprate(I)

Abstrakti

Pääsy asiakirjaan

Sormenjälki

Tietoaineistot

CCDC 1400760: Experimental Crystal Structure Determination

CCDC 1400759: Experimental Crystal Structure Determination

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