Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki; Aynur Guliyeva; Antti Korpi; Mauri Kostiainen; Ville Hynninen; Nonappa Nonappa; Patrice Rannou; Olli Ikkala; Sami Halia

doi:10.1039/C9CC04715H

Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki, Aynur Guliyeva, Antti Korpi, Mauri Kostiainen, Ville Hynninen, Nonappa Nonappa, Patrice Rannou, Olli Ikkala, Sami Halia

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

Abstrakti

We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

Alkuperäiskieli	Englanti
Sivut	11739-11742
Sivumäärä	4
Julkaisu	Chemical Communications
Vuosikerta	55
Numero	78
Varhainen verkossa julkaisun päivämäärä	5 elokuuta 2019
DOI - pysyväislinkit	https://doi.org/10.1039/C9CC04715H
Tila	Julkaistu - 2019
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1039/C9CC04715H

Sormenjälki Sukella tutkimusaiheisiin 'Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides'. Ne muodostavat yhdessä ainutlaatuisen sormenjäljen.

Projektit

1 Aktiivinen

DRIVEN: Field driven materials for functions, dissipation, and mimicking Pavlovian adaptation

Zhang, H., Peng, B., Som, A., Eklund, A., Ikkala, O., Ressouche, E., Gustavsson, L., Chandra, S., Srbova, L., Cherian, T. & Wani, O.

01/10/2017 → 31/12/2022

Projekti: EU: ERC grants

Laitteet

OtaNano

Anna Rissanen (Manager)

Aalto-yliopisto

Laitteistot/tilat: Facility

OtaNano Nanomikroskopiakeskus

Janne Ruokolainen (Manager)

Teknillisen fysiikan laitos

Laitteistot/tilat: Facility

Siteeraa tätä

Myllymäki, T. T. T., Guliyeva, A., Korpi, A., Kostiainen, M., Hynninen, V., Nonappa, N., ... Halia, S. (2019). Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides. Chemical Communications, 55(78), 11739-11742. https://doi.org/10.1039/C9CC04715H

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title = "Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides",

abstract = "We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.",

author = "Myllym{\"a}ki, {Teemu T. T.} and Aynur Guliyeva and Antti Korpi and Mauri Kostiainen and Ville Hynninen and Nonappa Nonappa and Patrice Rannou and Olli Ikkala and Sami Halia",

year = "2019",

doi = "10.1039/C9CC04715H",

language = "English",

volume = "55",

pages = "11739--11742",

journal = "Chemical Communications",

issn = "1359-7345",

number = "78",

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Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides. / Myllymäki, Teemu T. T.; Guliyeva, Aynur; Korpi, Antti ; Kostiainen, Mauri ; Hynninen, Ville ; Nonappa, Nonappa; Rannou, Patrice; Ikkala, Olli; Halia, Sami.

julkaisussa: Chemical Communications, Vuosikerta 55, Nro 78, 2019, s. 11739-11742.

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

TY - JOUR

T1 - Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

AU - Myllymäki, Teemu T. T.

AU - Guliyeva, Aynur

AU - Korpi, Antti

AU - Kostiainen, Mauri

AU - Hynninen, Ville

AU - Nonappa, Nonappa

AU - Rannou, Patrice

AU - Ikkala, Olli

AU - Halia, Sami

PY - 2019

Y1 - 2019

N2 - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

AB - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

U2 - 10.1039/C9CC04715H

DO - 10.1039/C9CC04715H

M3 - Article

C2 - 31513178

VL - 55

SP - 11739

EP - 11742

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 78

ER -