Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki; Aynur Guliyeva; Antti Korpi; Mauri Kostiainen; Ville Hynninen; Nonappa Nonappa; Patrice Rannou; Olli Ikkala; Sami Halia

doi:10.1039/C9CC04715H

Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki, Aynur Guliyeva, Antti Korpi, Mauri Kostiainen, Ville Hynninen, Nonappa Nonappa, Patrice Rannou, Olli Ikkala, Sami Halia

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

3 Sitaatiot (Scopus)

Abstrakti

We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

Alkuperäiskieli	Englanti
Sivut	11739-11742
Sivumäärä	4
Julkaisu	Chemical Communications
Vuosikerta	55
Numero	78
Varhainen verkossa julkaisun päivämäärä	5 elok. 2019
DOI - pysyväislinkit	https://doi.org/10.1039/C9CC04715H
Tila	Julkaistu - 2019
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1039/C9CC04715H

https://hal.archives-ouvertes.fr/hal-02998259/

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Koko teksti

1 Päättynyt

DRIVEN: Field driven materials for functions, dissipation, and mimicking Pavlovian adaptation
Ikkala, O., Fang, Y., Chandra, S., Cherian, T., Eklund, A., Girmay, S., Hu, S., Gustavsson, L., Hong, X., Ressouche, E., Lin, Z., Peng, B. & Liang, C.
01/10/2017 → 30/09/2022
Projekti: EU: ERC grants

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@article{880e69140ed448529145b5fcc8517514,

title = "Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides",

abstract = "We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.",

author = "Myllym{\"a}ki, {Teemu T. T.} and Aynur Guliyeva and Antti Korpi and Mauri Kostiainen and Ville Hynninen and Nonappa Nonappa and Patrice Rannou and Olli Ikkala and Sami Halia",

note = "| openaire: EC/H2020/742829/EU//DRIVEN",

year = "2019",

doi = "10.1039/C9CC04715H",

language = "English",

volume = "55",

pages = "11739--11742",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "78",

}

TY - JOUR

T1 - Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

AU - Myllymäki, Teemu T. T.

AU - Guliyeva, Aynur

AU - Korpi, Antti

AU - Kostiainen, Mauri

AU - Hynninen, Ville

AU - Nonappa, Nonappa

AU - Rannou, Patrice

AU - Ikkala, Olli

AU - Halia, Sami

N1 - | openaire: EC/H2020/742829/EU//DRIVEN

PY - 2019

Y1 - 2019

N2 - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

AB - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

U2 - 10.1039/C9CC04715H

DO - 10.1039/C9CC04715H

M3 - Article

C2 - 31513178

VL - 55

SP - 11739

EP - 11742

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 78

ER -

Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Abstrakti

Pääsy asiakirjaan

SFX-saatavuus

Sormenjälki

Projektit

DRIVEN: Field driven materials for functions, dissipation, and mimicking Pavlovian adaptation

Laitteet

OtaNano

OtaNano Nanomikroskopiakeskus

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