Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

Mikko Nisula; Jarno Linnera; Antti J. Karttunen; Maarit Karppinen

doi:10.1002/chem.201605816

Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

Mikko Nisula, Jarno Linnera, Antti J. Karttunen, Maarit Karppinen^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

25 Sitaatiot (Scopus)

535 Lataukset (Pure)

Abstrakti

Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

Alkuperäiskieli	Englanti
Sivut	2988 – 2992
Sivumäärä	5
Julkaisu	CHEMISTRY: A EUROPEAN JOURNAL
DOI - pysyväislinkit	https://doi.org/10.1002/chem.201605816
Tila	Julkaistu - 2017
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Pääsy asiakirjaan

10.1002/chem.201605816

ERC-27-acceptedAccepted author manuscript, 289 KBLisenssi: Määrittelemätön
ERC-27-accepted-Supporting-InfoFinal published version, 613 KBLisenssi: Määrittelemätön

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Link to publication in Scopus

Lithium Aryloxide Thin Films with Guest‐Induced Structural Transformation by ALD/MLD
Karttunen, A. (Creator) & Linnera, J. (Creator), NOMAD Repository, 2018
DOI - pysyväislinkki: 10.17172/NOMAD/2018.10.12-2
Tietoaineisto: Dataset

Uusia hybridimateriaaleja ALD/MLD:n avulla: perusteista sovelluksiin
Aleksandrova, I., Karppinen, M., Multia, J., Medina, E., Johansson, L., Revitzer, H., Haggren, A., Khayyami, A., Ghazy, A., Thomas, C., Tiittanen, T., Madadi, M., Mustonen, O. & Sederholm, L.
01/09/2016 → 31/08/2020
Projekti: Academy of Finland: Other research funding
CloseLoop: Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa
Karppinen, M., Kauranen, P., Kousar, S., Madadi, M., Blomberg, T. & Heiska, J.
01/04/2016 → 31/08/2019
Projekti: Academy of Finland: Strategic research funding
Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa
Karttunen, A. & Linnera, J.
01/04/2016 → 31/08/2019
Projekti: Academy of Finland: Strategic research funding

Raaka-aineiden tutkimusinfrastruktuuri
Maarit Karppinen (Manager)
Kemian tekniikan korkeakoulu
Laitteistot/tilat: Facility

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@article{dbf050d1c0bd4460bea82f5c37e2d836,

title = "Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD",

abstract = "Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.",

keywords = "Atomic layer deposition, Coordination polymer, Lithium organic hybrid, Molecular layer deposition, Thin film",

author = "Mikko Nisula and Jarno Linnera and Karttunen, {Antti J.} and Maarit Karppinen",

note = "| openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT ",

year = "2017",

doi = "10.1002/chem.201605816",

language = "English",

pages = "2988 – 2992",

journal = "CHEMISTRY: A EUROPEAN JOURNAL",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

AU - Nisula, Mikko

AU - Linnera, Jarno

AU - Karttunen, Antti J.

AU - Karppinen, Maarit

N1 - | openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT

PY - 2017

Y1 - 2017

N2 - Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

AB - Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

KW - Atomic layer deposition

KW - Coordination polymer

KW - Lithium organic hybrid

KW - Molecular layer deposition

KW - Thin film

UR - http://www.scopus.com/inward/record.url?scp=85011411866&partnerID=8YFLogxK

U2 - 10.1002/chem.201605816

DO - 10.1002/chem.201605816

M3 - Article

AN - SCOPUS:85011411866

SN - 0947-6539

SP - 2988

EP - 2992

JO - CHEMISTRY: A EUROPEAN JOURNAL

JF - CHEMISTRY: A EUROPEAN JOURNAL

ER -

Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

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Tietoaineistot

Lithium Aryloxide Thin Films with Guest‐Induced Structural Transformation by ALD/MLD

Projektit

Uusia hybridimateriaaleja ALD/MLD:n avulla: perusteista sovelluksiin

CloseLoop: Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa

Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa

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Raaka-aineiden tutkimusinfrastruktuuri

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