Layer-by-layer assembled hydrophobic coatings for cellulose nanofibril films and textiles, made of polylysine and natural wax particles

Nina Forsman, Alina Lozhechnikova, Alexey Khakalo, Leena-Sisko Johansson, Jari Vartiainen, Monika Österberg

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

40 Sitaatiot (Scopus)
336 Lataukset (Pure)

Abstrakti

Herein we present a simple method to render cellulosic materials highly hydrophobic while retaining their breathability and moisture buffering properties, thus allowing for their use as functional textiles. The surfaces are coated via layer-by-layer deposition of two natural components, cationic poly-l-lysine and anionic carnauba wax particles. The combination of multiscale roughness, open film structure, and low surface energy of wax colloids, resulted in long-lasting superhydrophobicity on cotton surface already after two bilayers. Atomic force microscopy, interference microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy were used to decouple structural effects from changes in surface energy. Furthermore, the effect of thermal annealing on the coating was evaluated. The potential of this simple and green approach to enhance the use of natural cellulosic materials is discussed.
AlkuperäiskieliEnglanti
Sivut392-402
Sivumäärä11
JulkaisuCarbohydrate Polymers
Vuosikerta173
DOI - pysyväislinkit
TilaJulkaistu - 2017
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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