Ionic and neutral fluorosurfactants containing ferrocene moieties as chromophoric constituents

Lukas Fliri, Gabriel Partl, Daniel Winkler, Klaus Wurst, Thomas Gelbrich, Thomas Müller, Herwig Schottenberger, Michael Hummel*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

1 Sitaatiot (Scopus)

Abstrakti

In two eventually interlinked projects emphasizing on the exploitation of the peculiar properties of ferrocene moieties, as well as fluoroponytails, the two compounds (E)-1-ferrocenyl-2-(1-(1H,1H,2H,2H-perfluorooctyl)-4-pyridiniumyl)ethylene hexafluorophosphate and (4-perfluorooctylphenyl)ferrocene were prepared. Despite the crystallization of polyfluoroalkylated materials is usually very challenging, attempts to grow single-crystals suitable for X-ray determination were successful, allowing for a detailed structural discussion of ferrocene containing fluorosurfactants for the first time. Additionally, a tentative UV–vis study was performed in four solvents. In contrast to the commonplace spectral behavior of (4-perfluorooctylphenyl)ferrocene, different interesting features, including slight solvatochromism, peak-splitting at higher concentrations, as well as the formation of a colored dispersion were detected for the ionic dye (E)-1-ferrocenyl-2-(1-(1H,1H,2H,2H-perfluorooctyl)-4-pyridiniumyl)ethylene hexafluorophosphate.

AlkuperäiskieliEnglanti
Artikkeli109674
Sivumäärä7
JulkaisuJournal of Fluorine Chemistry
Vuosikerta241
DOI - pysyväislinkit
TilaJulkaistu - tammikuuta 2021
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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