TY - JOUR
T1 - Intermolecular contrast in atomic force microscopy images without intermolecular bonds
AU - Hämäläinen, Sampsa
AU - van der Heijden, N.
AU - van der Lit, J.
AU - den Hartog, S.
AU - Liljeroth, P.
AU - Swart, I.
PY - 2014
Y1 - 2014
N2 - Intermolecular features in atomic force microscopy images of organic molecules have been ascribed to intermolecular bonds. A recent theoretical study [P. Hapala et al., Phys. Rev. B 90, 085421 (2014)] showed that these features can also be explained by the flexibility of molecule-terminated tips. We probe this effect by carrying out atomic force microscopy experiments on a model system that contains regions where intermolecular bonds should and should not exist between close-by molecules. Intermolecular features are observed in both regions, demonstrating that intermolecular contrast cannot be directly interpreted as intermolecular bonds.
AB - Intermolecular features in atomic force microscopy images of organic molecules have been ascribed to intermolecular bonds. A recent theoretical study [P. Hapala et al., Phys. Rev. B 90, 085421 (2014)] showed that these features can also be explained by the flexibility of molecule-terminated tips. We probe this effect by carrying out atomic force microscopy experiments on a model system that contains regions where intermolecular bonds should and should not exist between close-by molecules. Intermolecular features are observed in both regions, demonstrating that intermolecular contrast cannot be directly interpreted as intermolecular bonds.
KW - carbon monoxide (CO) -terminated tip
KW - hydrogen bond
KW - intermolecular contrast
KW - non-contact atomic force microscopy (AFM)
KW - carbon monoxide (CO) -terminated tip
KW - hydrogen bond
KW - intermolecular contrast
KW - non-contact atomic force microscopy (AFM)
KW - carbon monoxide (CO) -terminated tip
KW - hydrogen bond
KW - intermolecular contrast
KW - non-contact atomic force microscopy (AFM)
UR - http://dx.doi.org/10.1103/PhysRevLett.113.186102
U2 - 10.1103/PhysRevLett.113.186102
DO - 10.1103/PhysRevLett.113.186102
M3 - Article
SN - 0031-9007
VL - 113
SP - 1
EP - 5
JO - Physical Review Letters
JF - Physical Review Letters
M1 - 186102
ER -