Intermolecular contrast in atomic force microscopy images without intermolecular bonds

Sampsa Hämäläinen, N. van der Heijden, J. van der Lit, S. den Hartog, P. Liljeroth, I. Swart

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

127 Sitaatiot (Scopus)
239 Lataukset (Pure)

Abstrakti

Intermolecular features in atomic force microscopy images of organic molecules have been ascribed to intermolecular bonds. A recent theoretical study [P. Hapala et al., Phys. Rev. B 90, 085421 (2014)] showed that these features can also be explained by the flexibility of molecule-terminated tips. We probe this effect by carrying out atomic force microscopy experiments on a model system that contains regions where intermolecular bonds should and should not exist between close-by molecules. Intermolecular features are observed in both regions, demonstrating that intermolecular contrast cannot be directly interpreted as intermolecular bonds.
AlkuperäiskieliEnglanti
Artikkeli186102
Sivut1-5
JulkaisuPhysical Review Letters
Vuosikerta113
DOI - pysyväislinkit
TilaJulkaistu - 2014
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Tutkimusalat

  • carbon monoxide (CO) -terminated tip
  • hydrogen bond
  • intermolecular contrast
  • non-contact atomic force microscopy (AFM)

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