Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran

Hong Chen; Yingying Li; Linhao Yu; Sen Wang; Xueli Ma; Can Wang; Yongdan Li

doi:10.1007/s10562-022-03945-0

Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran

Hong Chen^*, Yingying Li, Linhao Yu, Sen Wang, Xueli Ma, Can Wang, Yongdan Li

^*Tämän työn vastaava kirjoittaja

Tianjin University

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

2 Sitaatiot (Scopus)

67 Lataukset (Pure)

Abstrakti

A series of hydroxyapatite (HAP) supports with different Ca/P ratios were synthesized to prepare the MnO_x/HAP catalysts. A MnO_x/HAP catalyst showed highly efficient conversion of 5-hydroxymethylfurfural (HMF) into 2, 5-diformylfuran (DFF) in toluene solvent under no-alkali condition. 86.4% conversion of HMF with 90.9% selectivity of DFF at 120 °C for 12 h under 1.0 MPa O₂ over the MnO_x/HAP-10.0-400 were obtained. The redox of Mn⁴⁺/Mn³⁺ improved the oxidation of 5-HMF to DFF by the lattice oxygen, and the lattice oxygen was replenished by adsorbing O₂ molecules. The reusability tests were found the catalyst could be reused up to four cycles without notable loss of catalytic activity. The MnO_x/HAP-10.0-400 was a stable and reusable material for further industrial exploration of DFF in an environmentally friendly way.

Alkuperäiskieli	Englanti
Sivut	3716-3724
Sivumäärä	9
Julkaisu	Catalysis Letters
Vuosikerta	152
Numero	12
Varhainen verkossa julkaisun päivämäärä	12 helmik. 2022
DOI - pysyväislinkit	https://doi.org/10.1007/s10562-022-03945-0
Tila	Julkaistu - jouluk. 2022
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

YK:n kestävän kehityksen tavoitteet

Tämä tuotos edistää seuraavia kestävän kehityksen tavoitteita:

Pääsy asiakirjaan

10.1007/s10562-022-03945-0

CHEM_Chen_et_al_Hydroxyapatite_Supported_Manganese_Oxide_2022_Catalysis_LettersAccepted author manuscript, 1,9 MBLisenssi: Määrittelemätön

Muut tiedostot ja linkit

Linkki julkaisuun Scopuksessa

Siteeraa tätä

@article{b46d40ee8dac4003a39e5c0daa6d4ae8,

title = "Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran",

abstract = "A series of hydroxyapatite (HAP) supports with different Ca/P ratios were synthesized to prepare the MnOx/HAP catalysts. A MnOx/HAP catalyst showed highly efficient conversion of 5-hydroxymethylfurfural (HMF) into 2, 5-diformylfuran (DFF) in toluene solvent under no-alkali condition. 86.4% conversion of HMF with 90.9% selectivity of DFF at 120 °C for 12 h under 1.0 MPa O2 over the MnOx/HAP-10.0-400 were obtained. The redox of Mn4+/Mn3+ improved the oxidation of 5-HMF to DFF by the lattice oxygen, and the lattice oxygen was replenished by adsorbing O2 molecules. The reusability tests were found the catalyst could be reused up to four cycles without notable loss of catalytic activity. The MnOx/HAP-10.0-400 was a stable and reusable material for further industrial exploration of DFF in an environmentally friendly way.",

keywords = "2, 5-Diformylfuran, 5-hydroxymethylfurfural, Base-free, Hydroxyapatite, Selective oxidation",

author = "Hong Chen and Yingying Li and Linhao Yu and Sen Wang and Xueli Ma and Can Wang and Yongdan Li",

note = "Funding Information: The research was supported by the Natural Science Foundation of China (21808163 and 21690083). Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2022",

month = dec,

doi = "10.1007/s10562-022-03945-0",

language = "English",

volume = "152",

pages = "3716--3724",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer",

number = "12",

}

TY - JOUR

T1 - Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran

AU - Chen, Hong

AU - Li, Yingying

AU - Yu, Linhao

AU - Wang, Sen

AU - Ma, Xueli

AU - Wang, Can

AU - Li, Yongdan

N1 - Funding Information: The research was supported by the Natural Science Foundation of China (21808163 and 21690083). Publisher Copyright: © 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2022/12

Y1 - 2022/12

N2 - A series of hydroxyapatite (HAP) supports with different Ca/P ratios were synthesized to prepare the MnOx/HAP catalysts. A MnOx/HAP catalyst showed highly efficient conversion of 5-hydroxymethylfurfural (HMF) into 2, 5-diformylfuran (DFF) in toluene solvent under no-alkali condition. 86.4% conversion of HMF with 90.9% selectivity of DFF at 120 °C for 12 h under 1.0 MPa O2 over the MnOx/HAP-10.0-400 were obtained. The redox of Mn4+/Mn3+ improved the oxidation of 5-HMF to DFF by the lattice oxygen, and the lattice oxygen was replenished by adsorbing O2 molecules. The reusability tests were found the catalyst could be reused up to four cycles without notable loss of catalytic activity. The MnOx/HAP-10.0-400 was a stable and reusable material for further industrial exploration of DFF in an environmentally friendly way.

AB - A series of hydroxyapatite (HAP) supports with different Ca/P ratios were synthesized to prepare the MnOx/HAP catalysts. A MnOx/HAP catalyst showed highly efficient conversion of 5-hydroxymethylfurfural (HMF) into 2, 5-diformylfuran (DFF) in toluene solvent under no-alkali condition. 86.4% conversion of HMF with 90.9% selectivity of DFF at 120 °C for 12 h under 1.0 MPa O2 over the MnOx/HAP-10.0-400 were obtained. The redox of Mn4+/Mn3+ improved the oxidation of 5-HMF to DFF by the lattice oxygen, and the lattice oxygen was replenished by adsorbing O2 molecules. The reusability tests were found the catalyst could be reused up to four cycles without notable loss of catalytic activity. The MnOx/HAP-10.0-400 was a stable and reusable material for further industrial exploration of DFF in an environmentally friendly way.

KW - 2, 5-Diformylfuran

KW - 5-hydroxymethylfurfural

KW - Base-free

KW - Hydroxyapatite

KW - Selective oxidation

UR - http://www.scopus.com/inward/record.url?scp=85124431201&partnerID=8YFLogxK

U2 - 10.1007/s10562-022-03945-0

DO - 10.1007/s10562-022-03945-0

M3 - Article

AN - SCOPUS:85124431201

SN - 1011-372X

VL - 152

SP - 3716

EP - 3724

JO - Catalysis Letters

JF - Catalysis Letters

IS - 12

ER -

Hydroxyapatite Supported Manganese Oxide as a Heterogeneous Catalyst for the Synthesis of 2, 5-Diformylfuran

Abstrakti

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Siteeraa tätä