Hydrogenation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid sodium salt attached to xylodiose or xylotriose

Sami A. Selkälä, Sami Alakurtti, Ari M.P. Koskinen

    Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

    92 Lataukset (Pure)

    Abstrakti

    A sodium salt of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid 1 attached to xylodiose or xylotriose is hydro-genated for the first time. Moreover, the double bond of 4-deoxy-b-L-threo -hex-4-enopyranosyluronic acid sodium salt 1 can be reduced by hydrogenation in water without removing the allylic hydroxyl group. Highly active homogeneous catalysts and heterogeneous catalysts were tested and only palladium or platinum on charcoal catalysts were found to be active in this case.
    AlkuperäiskieliEnglanti
    Sivut3215-3217
    JulkaisuTetrahedron Letters
    Vuosikerta42
    DOI - pysyväislinkit
    TilaJulkaistu - 2001
    OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

    Tutkimusalat

    • heterogenous catalysis
    • homogenous catalysis
    • hydrogenation
    • unsaturated acid

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