Hydration layers at the graphite-water interface: Attraction or confinement

Hagen Soengen*, Ygor Morais Jaques, Lidija Zivanovic, Sebastian Seibert, Ralf Bechstein, Peter Spijker, Hiroshi Onishi, Adam S. Foster, Angelika Kuehnle

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

1 Sitaatiot (Scopus)
21 Lataukset (Pure)

Abstrakti

Water molecules at solid surfaces typically arrange in layers. The physical origin of the hydration layers is usually explained by two different reasons: (1) the attraction between the surface and water and (2) the water confinement due to the surface. While the attraction is specific to the particular solid, the confinement is a general property of surfaces; a differentiation between the two effects is, therefore, critical for research on interactions at aqueous interfaces. Here, we investigate the graphite-water interface, which is a widely used model system where the solid-water attraction is often considered to be negligible Similar to previous studies, we observe hydration layers using three-dimensional atomic force microscopy at the graphite-water interface. We explain why the confinement could cause the formation of hydration layers even in the absence of attraction between surface and water by employing Monte Carlo simulations. Using additional molecular dynamics simulations, we continue to show that at ambient conditions, however, the confinement alone does not cause the formation of layers at the graphite-water interface. We thereby demonstrate that there is a significant graphite-water attraction.

AlkuperäiskieliEnglanti
Artikkeli205410
Sivumäärä8
JulkaisuPhysical Review B
Vuosikerta100
Numero20
DOI - pysyväislinkit
TilaJulkaistu - 8 marraskuuta 2019
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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  • Siteeraa tätä

    Soengen, H., Jaques, Y. M., Zivanovic, L., Seibert, S., Bechstein, R., Spijker, P., ... Kuehnle, A. (2019). Hydration layers at the graphite-water interface: Attraction or confinement. Physical Review B, 100(20), [205410]. https://doi.org/10.1103/PhysRevB.100.205410