Halogen bonding modulates hydrogel formation from Fmoc amino acids

A. Pizzi; L. Lascialfari; N. Demitri; A. Bertolani; D. Maiolo; E. Carretti; P. Metrangolo

doi:10.1039/c7ce00031f

Halogen bonding modulates hydrogel formation from Fmoc amino acids

A. Pizzi
, L. Lascialfari
, N. Demitri
, A. Bertolani
, D. Maiolo
, E. Carretti
, P. Metrangolo^*

^*Tämän työn vastaava kirjoittaja

Teknillisen fysiikan laitos

Polytechnic University of Milan
Sincrotrone Trieste
University of Florence

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

46 Sitaatiot (Scopus)

Abstrakti

The single crystal X-ray structures of a series of p-halogenated Fmoc phenylalanines highlight the role of halogen bonding in their supramolecular organization in the solid state. The amino acids showing the occurrence of halogen bonding resulted in gels with the strongest mechanical properties. All gelation parameters could be ranked according to halogen atom polarizability, i.e., halogen bond strength.

Alkuperäiskieli	Englanti
Sivut	1870-1874
Sivumäärä	5
Julkaisu	CrystEngComm
Vuosikerta	19
Numero	14
DOI - pysyväislinkit	https://doi.org/10.1039/c7ce00031f
Tila	Julkaistu - 2017
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Pääsy asiakirjaan

10.1039/c7ce00031f

Muut tiedostot ja linkit

Link to publication in Scopus

CCDC 1521993: Experimental Crystal Structure Determination
Bertolani, A. (Contributor), Carretti, E. (Contributor), Demitri, N. (Contributor), Lascialfari, L. (Contributor), Maiolo, D. (Contributor), Metrangolo, P. (Creator) & Pizzi, A. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2017
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1n2rk1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1n2rk1&sid=DataCite
Tietoaineisto: Dataset
CCDC 1521995: Experimental Crystal Structure Determination
Bertolani, A. (Contributor), Carretti, E. (Contributor), Demitri, N. (Contributor), Lascialfari, L. (Contributor), Maiolo, D. (Contributor), Metrangolo, P. (Creator) & Pizzi, A. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2017
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1n2rm3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1n2rm3&sid=DataCite
Tietoaineisto: Dataset
CCDC 1521994: Experimental Crystal Structure Determination
Bertolani, A. (Contributor), Carretti, E. (Contributor), Demitri, N. (Contributor), Lascialfari, L. (Contributor), Maiolo, D. (Contributor), Metrangolo, P. (Creator) & Pizzi, A. (Contributor), Cambridge Crystallographic Data Centre , 1 tammik. 2017
DOI - pysyväislinkki: 10.5517/ccdc.csd.cc1n2rl2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1n2rl2&sid=DataCite
Tietoaineisto: Dataset

Siteeraa tätä

@article{616df7eaaf6a4f61b65b4926315a5824,

title = "Halogen bonding modulates hydrogel formation from Fmoc amino acids",

abstract = "The single crystal X-ray structures of a series of p-halogenated Fmoc phenylalanines highlight the role of halogen bonding in their supramolecular organization in the solid state. The amino acids showing the occurrence of halogen bonding resulted in gels with the strongest mechanical properties. All gelation parameters could be ranked according to halogen atom polarizability, i.e., halogen bond strength.",

author = "A. Pizzi and L. Lascialfari and N. Demitri and A. Bertolani and D. Maiolo and E. Carretti and P. Metrangolo",

year = "2017",

doi = "10.1039/c7ce00031f",

language = "English",

volume = "19",

pages = "1870--1874",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Halogen bonding modulates hydrogel formation from Fmoc amino acids

AU - Pizzi, A.

AU - Lascialfari, L.

AU - Demitri, N.

AU - Bertolani, A.

AU - Maiolo, D.

AU - Carretti, E.

AU - Metrangolo, P.

PY - 2017

Y1 - 2017

N2 - The single crystal X-ray structures of a series of p-halogenated Fmoc phenylalanines highlight the role of halogen bonding in their supramolecular organization in the solid state. The amino acids showing the occurrence of halogen bonding resulted in gels with the strongest mechanical properties. All gelation parameters could be ranked according to halogen atom polarizability, i.e., halogen bond strength.

AB - The single crystal X-ray structures of a series of p-halogenated Fmoc phenylalanines highlight the role of halogen bonding in their supramolecular organization in the solid state. The amino acids showing the occurrence of halogen bonding resulted in gels with the strongest mechanical properties. All gelation parameters could be ranked according to halogen atom polarizability, i.e., halogen bond strength.

UR - https://www.scopus.com/pages/publications/85016951080

U2 - 10.1039/c7ce00031f

DO - 10.1039/c7ce00031f

M3 - Article

AN - SCOPUS:85016951080

SN - 1466-8033

VL - 19

SP - 1870

EP - 1874

JO - CrystEngComm

JF - CrystEngComm

IS - 14

ER -

Halogen bonding modulates hydrogel formation from Fmoc amino acids

Abstrakti

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Tietoaineistot

CCDC 1521993: Experimental Crystal Structure Determination

CCDC 1521995: Experimental Crystal Structure Determination

CCDC 1521994: Experimental Crystal Structure Determination

Siteeraa tätä