TY - JOUR
T1 - Functionalized cellulose nanofiber films as potential substitutes for Japanese paper
AU - Almeida, Ricardo
AU - Ramos, Ana
AU - Håkonsen, Verner
AU - Maloney, Thaddeus
AU - Gamelas, José
N1 - Publisher Copyright:
© 2024
PY - 2024/12
Y1 - 2024/12
N2 - Japanese papers (JPs) are among the most common materials used for the restoration of historical papers. However, they have low transparency and may structure the paper surface. To overcome the limitations of JPs, in the present work films of cellulose nanofibers with and without lignin (LCNFs and CNFs, respectively) were explored. For this, chemically different LCNFs (carboxylated by TEMPO-mediated oxidation using variable oxidant amount and sulfated with deep eutectic solvent) and two reference CNFs were produced from Eucalyptus kraft pulps. Lignin slightly hindered the introduction of carboxyl groups into the cellulose structure, but did not affect the incorporation of sulfate groups. (L)CNFs gave films with better mechanical properties than those determined for three types of JP (tensile strength of 79–142 MPa (±11) vs 3.5–13.0 MPa (±0.4) and Young's modulus of 4900–5900 MPa (±300) vs 240–1800 MPa (±70)). Additionally, the (L)CNF films exhibited lower water vapor transmission rates (132–312 g.m−2.day−1) compared to the JPs (685–719 g.m−2.day−1), and a higher transparency (up to 89% and ≤82% for JPs). Except for the thermal stability, all properties studied favored (L)CNF films over JPs, indicating their strong potential for restoration/conservation applications. This systematic comparison between the properties of (L)CNF films and JPs has never been conducted before.
AB - Japanese papers (JPs) are among the most common materials used for the restoration of historical papers. However, they have low transparency and may structure the paper surface. To overcome the limitations of JPs, in the present work films of cellulose nanofibers with and without lignin (LCNFs and CNFs, respectively) were explored. For this, chemically different LCNFs (carboxylated by TEMPO-mediated oxidation using variable oxidant amount and sulfated with deep eutectic solvent) and two reference CNFs were produced from Eucalyptus kraft pulps. Lignin slightly hindered the introduction of carboxyl groups into the cellulose structure, but did not affect the incorporation of sulfate groups. (L)CNFs gave films with better mechanical properties than those determined for three types of JP (tensile strength of 79–142 MPa (±11) vs 3.5–13.0 MPa (±0.4) and Young's modulus of 4900–5900 MPa (±300) vs 240–1800 MPa (±70)). Additionally, the (L)CNF films exhibited lower water vapor transmission rates (132–312 g.m−2.day−1) compared to the JPs (685–719 g.m−2.day−1), and a higher transparency (up to 89% and ≤82% for JPs). Except for the thermal stability, all properties studied favored (L)CNF films over JPs, indicating their strong potential for restoration/conservation applications. This systematic comparison between the properties of (L)CNF films and JPs has never been conducted before.
KW - Cellulose nanofibrils
KW - Deep eutectic solvent
KW - Lignin-containing cellulose nanofibers
KW - Nanocellulose
KW - Nanopapers
KW - Paper conservation
KW - Paper restoration
KW - TEMPO-mediated oxidation
UR - http://www.scopus.com/inward/record.url?scp=85206633055&partnerID=8YFLogxK
U2 - 10.1016/j.carpta.2024.100573
DO - 10.1016/j.carpta.2024.100573
M3 - Article
AN - SCOPUS:85206633055
SN - 2666-8939
VL - 8
JO - Carbohydrate Polymer Technologies and Applications
JF - Carbohydrate Polymer Technologies and Applications
M1 - 100573
ER -