2 Sitaatiot (Scopus)
60 Lataukset (Pure)

Abstrakti

The electronic and optical properties of low-dimensional semiconductors are typically quite different from those of their bulk counterparts. Yet, the optical gap of two-dimensional copper antimony disulfide (CuSbS2) does not dramatically change with decreasing thickness of the material. The absorption onset remains at about 1.5 eV in the monolayer, bilayer, and bulk materials. Using density functional theory and many-body perturbation theory, we rationalize this behavior through the interplay of quantum confinement, electron-hole interactions, and the formation of surface states. Specifically, the spatial confinement in thin layers induces strongly bound optical transitions in the near-infrared region. Our results explain the optical properties in copper antimony disulfide platelets of varying thickness and set these materials as potential candidates for novel photovoltaic devices and near-infrared sensors.

AlkuperäiskieliEnglanti
Sivut21087–21092
Sivumäärä6
JulkaisuJournal of Physical Chemistry C
Vuosikerta125
Numero38
Varhainen verkossa julkaisun päivämäärä20 syysk. 2021
DOI - pysyväislinkit
TilaJulkaistu - 30 syysk. 2021
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Sormenjälki

Sukella tutkimusaiheisiin 'Formation of Near-IR Excitons in Low-Dimensional CuSbS2'. Ne muodostavat yhdessä ainutlaatuisen sormenjäljen.

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