Flexible and Mechanically Durable Asymmetric Supercapacitor Based on NiCo-Layered Double Hydroxide and Nitrogen-Doped Graphene Using a Simple Fabrication Method

Bahareh Mehrabimatin, Evgenia P. Gilshteyn, Marthe Emelie Melandsø Buan, Olli Sorsa, Hua Jiang, Azam Iraji zad, Saeed Shahrokhian, Albert G. Nasibulin, Tanja Kallio*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

8 Sitaatiot (Scopus)

Abstrakti

A high-performing, lightweight, and flexible asymmetric supercapacitor (ASC) using NiCo-layered double hydroxide (NiCo LDH) supported on 3D nitrogen-doped graphene (NG) as a positive electrode and NG as a negative electrode is demonstrated. Highly conductive NG provides fast electron transfer and facilitates (dis)charging of NiCo LDH deposited on it. The composite electrode of NiCo LDH@NG exhibits a high specific capacitance of 1421 F g −1 at 2 A g −1 . Moreover, the as-obtained hybrid electrode shows an excellent rate capability with a specific capacitance of 1397 F g −1 at a high current density of 10 A g −1 , which is about 98% of the capacitance obtained at 2 A g −1 . The flexible ASC device shows a specific capacitance of 109 F g −1 at 0.5 A g −1 and a maximum energy density of 49 W h kg −1 , which is comparable with or superior to previously reported electrodes based on nickel-cobalt hydroxides. Furthermore, an excellent mechanical stability is obtained. Under repeated mechanical bendings, the ASC demonstrates high bending stability up to 450 bending cycles at a 90° angle. Hence, this flexible NiCo LDH@NG electrode that is free of binders and conductive agents shows superior performance and stability, and is a promising candidate for the future wearable energy storage devices.

AlkuperäiskieliEnglanti
Artikkeli1801002
Sivumäärä13
JulkaisuEnergy Technology
Vuosikerta7
Numero5
DOI - pysyväislinkit
TilaJulkaistu - 1 huhtikuuta 2019
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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  • Projektit

    • 2 Päättynyt

    Korkean jalostusarvon materiaalit suljetussa raaka-ainekierrossa

    Lahtinen, K., Kallio, T. & Revitzer, H.

    01/04/201623/09/2019

    Projekti: Academy of Finland: Strategic research funding

    Platina ryhmän metalleja sisältämättömien katalyyttien kehittäminen kestävän kehityksen turvaamiseksi

    Sorsa, O., Kallio, T., Rauhala, T. & Davodi, F.

    01/09/201523/09/2019

    Projekti: Academy of Finland: Other research funding

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