Fast formation of a supramolecular ion gel/solvoplastic elastomer with excellent stretchability

Tutkimustuotos: Lehtiartikkelivertaisarvioitu

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Fast formation of a supramolecular ion gel/solvoplastic elastomer with excellent stretchability. / Bai, Shishun; Wang, Xin; Vapaavuori, Jaana; He, Xianru.

julkaisussa: Royal Society Open Science, Vuosikerta 5, Nro 6, 180271, 06.2018.

Tutkimustuotos: Lehtiartikkelivertaisarvioitu

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Bibtex - Lataa

@article{3001bc737a6146998a8d8f766ed1ef45,
title = "Fast formation of a supramolecular ion gel/solvoplastic elastomer with excellent stretchability",
abstract = "This study describes a simple yet efficient approach for the preparation of an ionic gel that is also elastomeric in its solid-state bulk form. A series of poly(2-(diethylamino)ethyl methacrylate-eo-lauryl methacrylate) P(DMAEMA-co-LMA) copolymers were synthesized first by radical polymerization. Quaternization of the PDMAEMA component in tetrahydrofuran enables the formation of supramolecular network, giving rise to an ion gel. An elastomer with an elongation at break of over 600{\%} was obtained from the gel. The elastomer, connected by supramolecular ionic cross-links, is solvoplastic in certain solvents. The simple yet efficient approach of the formation of ion-gel and the dried elastomer allows fast preparation of both gel-like and solid-state elastic materials for various applications where recyclability is required.",
keywords = "supramolecular ion gel, random copolymer, quaternization, solvoplastic elastomer, VISCOELASTIC PROPERTIES, RHEOLOGICAL PROPERTIES, POLYMER ELECTROLYTES, GEL, HYDROGELS, COPOLYMER, METHACRYLATE, LIQUID, TRANSITION, BATTERIES",
author = "Shishun Bai and Xin Wang and Jaana Vapaavuori and Xianru He",
year = "2018",
month = "6",
doi = "10.1098/rsos.180271",
language = "English",
volume = "5",
journal = "Royal Society Open Science",
issn = "2054-5703",
number = "6",

}

RIS - Lataa

TY - JOUR

T1 - Fast formation of a supramolecular ion gel/solvoplastic elastomer with excellent stretchability

AU - Bai, Shishun

AU - Wang, Xin

AU - Vapaavuori, Jaana

AU - He, Xianru

PY - 2018/6

Y1 - 2018/6

N2 - This study describes a simple yet efficient approach for the preparation of an ionic gel that is also elastomeric in its solid-state bulk form. A series of poly(2-(diethylamino)ethyl methacrylate-eo-lauryl methacrylate) P(DMAEMA-co-LMA) copolymers were synthesized first by radical polymerization. Quaternization of the PDMAEMA component in tetrahydrofuran enables the formation of supramolecular network, giving rise to an ion gel. An elastomer with an elongation at break of over 600% was obtained from the gel. The elastomer, connected by supramolecular ionic cross-links, is solvoplastic in certain solvents. The simple yet efficient approach of the formation of ion-gel and the dried elastomer allows fast preparation of both gel-like and solid-state elastic materials for various applications where recyclability is required.

AB - This study describes a simple yet efficient approach for the preparation of an ionic gel that is also elastomeric in its solid-state bulk form. A series of poly(2-(diethylamino)ethyl methacrylate-eo-lauryl methacrylate) P(DMAEMA-co-LMA) copolymers were synthesized first by radical polymerization. Quaternization of the PDMAEMA component in tetrahydrofuran enables the formation of supramolecular network, giving rise to an ion gel. An elastomer with an elongation at break of over 600% was obtained from the gel. The elastomer, connected by supramolecular ionic cross-links, is solvoplastic in certain solvents. The simple yet efficient approach of the formation of ion-gel and the dried elastomer allows fast preparation of both gel-like and solid-state elastic materials for various applications where recyclability is required.

KW - supramolecular ion gel

KW - random copolymer

KW - quaternization

KW - solvoplastic elastomer

KW - VISCOELASTIC PROPERTIES

KW - RHEOLOGICAL PROPERTIES

KW - POLYMER ELECTROLYTES

KW - GEL

KW - HYDROGELS

KW - COPOLYMER

KW - METHACRYLATE

KW - LIQUID

KW - TRANSITION

KW - BATTERIES

U2 - 10.1098/rsos.180271

DO - 10.1098/rsos.180271

M3 - Article

VL - 5

JO - Royal Society Open Science

JF - Royal Society Open Science

SN - 2054-5703

IS - 6

M1 - 180271

ER -

ID: 32394166