Experimental thermodynamic study on the Ag-Sb system at elevated temperatures

Tutkimustuotos: Artikkeli kirjassa/konferenssijulkaisussaConference contributionScientificvertaisarvioitu

Abstrakti

In this paper, the standard thermodynamic properties of Ag3Sb and Ag6Sb intermetallic compounds have been studied by the solid state EMF-method, using Ag+ ion conducting β- Alumina and Ag+. The intermetallic compounds were synthesized from pure substances in evacuated silica ampoules and their formation were confirmed by the SEM-EDS analyses. The EMF measurements were made on electrochemical cells of the type [Ag | β-alumina | Ag-Sb] and [Ag | Agl | Ag-Sb], The usage of β-alumina electrolyte, in this study, enabled thermodynamic measurements of the Ag-Sb-intermetallic compounds above 710 K, hitherto unreported. Based on the new experimental data, thermodynamic properties of the Ag-Sb-intermetallic compounds have been determined. The obtained experimental values have been compared with the available literature data.

AlkuperäiskieliEnglanti
OtsikkoEPD Congress 2015 - Held During TMS 2015 144th Annual Meeting and Exhibition
KustantajaMINERALS, METALS AND MATERIALS SOCIETY
Sivut305-312
Sivumäärä8
Vuosikerta2015-January
PainosJanuary
ISBN (elektroninen)9781119093503
ISBN (painettu)9781119082453
DOI - pysyväislinkit
TilaJulkaistu - 2015
OKM-julkaisutyyppiA4 Artikkeli konferenssijulkaisuussa
TapahtumaTMS Annual Meeting and Exhibition - Orlando, Yhdysvallat
Kesto: 15 maaliskuuta 201519 maaliskuuta 2015
Konferenssinumero: 144

Conference

ConferenceTMS Annual Meeting and Exhibition
LyhennettäTMS
MaaYhdysvallat
KaupunkiOrlando
Ajanjakso15/03/201519/03/2015

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