Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios

J. V. Seppälä

doi:10.1021/ma00154a012

Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios

J. V. Seppälä^*

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Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

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The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C₁₀, C₁₂, and C₁₆ α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by ¹³C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

Alkuperäiskieli	Englanti
Sivut	2409-2412
Sivumäärä	4
Julkaisu	Macromolecules
Vuosikerta	18
Numero	12
DOI - pysyväislinkit	https://doi.org/10.1021/ma00154a012
Tila	Julkaistu - 1985
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

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10.1021/ma00154a012

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@article{13052d047e424a0b81c1c765bccd8c66,

title = "Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios",

abstract = "The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.",

author = "Sepp{\"a}l{\"a}, {J. V.}",

year = "1985",

doi = "10.1021/ma00154a012",

language = "English",

volume = "18",

pages = "2409--2412",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "AMERICAN CHEMICAL SOCIETY",

number = "12",

}

TY - JOUR

T1 - Ethylene terpolymerization with 1-butene and long-chain α-olefins

T2 - Reactivity ratios

AU - Seppälä, J. V.

PY - 1985

Y1 - 1985

N2 - The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

AB - The terpolymerization equation has been applied to ethylene terpolymerization with 1-butene and C10, C12, and C16 α-olefins. The six binary reactivity ratios in the terpolymerization equation were determined by a computer search for each terpolymerization. The calculated polymer compositions were compared with the compositions determined by 13C NMR spectroscopy, and the results generally agreed within 1 wt %. The terpolymerization behavior could be explained with the determined reactivity ratios and the terpolymerization equation.

UR - http://www.scopus.com/inward/record.url?scp=4043181672&partnerID=8YFLogxK

U2 - 10.1021/ma00154a012

DO - 10.1021/ma00154a012

M3 - Article

AN - SCOPUS:4043181672

VL - 18

SP - 2409

EP - 2412

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 12

ER -

Ethylene terpolymerization with 1-butene and long-chain α-olefins: Reactivity ratios

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