Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior

Zulin Wang; Kirsi Yliniemi; Eeva-Leena Rautama; Pyry-Mikko Hannula; Benjamin P. Wilson; Mari Lundström

doi:10.1021/acssuschemeng.2c00284

Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior

Zulin Wang, Kirsi Yliniemi, Eeva-Leena Rautama, Pyry-Mikko Hannula, Benjamin P. Wilson, Mari Lundström^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

7 Sitaatiot (Scopus)

132 Lataukset (Pure)

Abstrakti

This study investigates the sustainable preparation of Ag/Zn alloys from a simulated zinc process solution (20 ppm Ag, 65 g/L Zn, and 10 g/L H₂SO₄) via electrodeposition-redox replacement (EDRR) and the electrochemical dealloying behavior of the Ag/Zn alloys. Results indicate that Ag/Zn deposits with diverse compositions and microstructures can be obtained at room temperature without any complexing agents, simply by varying EDRR parameters like deposition time,
deposition potential, and redox replacement time. Two types of Ag/Zn intermetallics (Zn_0.96Ag_0.04 and Ag_0.76Zn0_.24) were identified by the combination of X-ray diffraction (XRD) and anodic linear sweep voltammetry. Mass-transfer limitations have significant effects on the growth process, and a nucleation-growth mechanism from Ag/Zn particles into dendrites with increased EDRR cycles is introduced: with EDRR parameters favoring mass-transfer limitations (higher overpotentials, longer deposition times, and shorter redox replacement times), a more dendritic morphology of Ag/Zn alloys is achieved. The selective dissolution of Zn (i.e. dealloying) allowed the formation of silver-rich surfaces with an enhanced surface plasmon resonance behavior, which can be readily tuned by EDRR and dealloying parameters. These results highlight the significant potential of the EDRR-dealloying route to produce different types of Ag/Zn alloys and optically functional materials directly from
base metal process solutions.

Alkuperäiskieli	Englanti
Sivut	3716–3725
Sivumäärä	10
Julkaisu	ACS Sustainable Chemistry and Engineering
Vuosikerta	10
Numero	11
Varhainen verkossa julkaisun päivämäärä	7 maalisk. 2022
DOI - pysyväislinkit	https://doi.org/10.1021/acssuschemeng.2c00284
Tila	Julkaistu - 21 maalisk. 2022
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.1021/acssuschemeng.2c00284Lisenssi: CC BY

CHEM_Wang_et_al_Electrochemical_Growth_of_AgZn_Alloys_2022_ACS_Sustainable_Chem_EngFinal published version, 9,45 MBLisenssi: CC BY

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Dataset Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior
Wang, Z. (Creator), Yliniemi, K. (Creator), Rautama, E.-L. (Creator), Hannula, P.-M. (Creator), Wilson, B. (Creator) & Lundström, M. (Creator), Zenodo, 11 lokak. 2021
DOI - pysyväislinkki: 10.5281/zenodo.5561033, https://zenodo.org5561034
Tietoaineisto: Dataset

1 Päättynyt
1 Aktiivinen

EARMetal, Hydro: Electrochemically Assisted Aqueous Reduction of Waste Streams for Metals Recovery and Functional Surfaces
Lundström, M. (Vastuullinen tutkija), Herrala, R. (Projektin jäsen), Cui, L. (Projektin jäsen), Yliniemi, K. (Projektin jäsen) & Wang, Z. (Projektin jäsen)
01/09/2021 → 31/08/2025
Projekti: Academy of Finland: Other research funding
GoldTail: Kultapitoisten rikastushiekkojen kestävä hyödyntäminen (GoldTail)
Lundström, M. (Vastuullinen tutkija), Yliniemi, K. (Projektin jäsen), Halli, P. (Projektin jäsen), Karppinen, A. (Projektin jäsen), Revitzer, H. (Projektin jäsen), Wilson, B. (Projektin jäsen), Seisko, S. (Projektin jäsen), Sahlman, M. (Projektin jäsen) & Wang, Z. (Projektin jäsen)
01/10/2018 → 30/09/2021
Projekti: Academy of Finland: Other research funding

Raaka-aineiden tutkimusinfrastruktuuri
Karppinen, M. (Manager)
Kemian tekniikan korkeakoulu
Laitteistot/tilat: Facility

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@article{9effa121136a4888bdbd554cf1cc8500,

title = "Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior",

abstract = "This study investigates the sustainable preparation of Ag/Zn alloys from a simulated zinc process solution (20 ppm Ag, 65 g/L Zn, and 10 g/L H2SO4) via electrodeposition-redox replacement (EDRR) and the electrochemical dealloying behavior of the Ag/Zn alloys. Results indicate that Ag/Zn deposits with diverse compositions and microstructures can be obtained at room temperature without any complexing agents, simply by varying EDRR parameters like deposition time,deposition potential, and redox replacement time. Two types of Ag/Zn intermetallics (Zn0.96Ag0.04 and Ag0.76Zn0.24) were identified by the combination of X-ray diffraction (XRD) and anodic linear sweep voltammetry. Mass-transfer limitations have significant effects on the growth process, and a nucleation-growth mechanism from Ag/Zn particles into dendrites with increased EDRR cycles is introduced: with EDRR parameters favoring mass-transfer limitations (higher overpotentials, longer deposition times, and shorter redox replacement times), a more dendritic morphology of Ag/Zn alloys is achieved. The selective dissolution of Zn (i.e. dealloying) allowed the formation of silver-rich surfaces with an enhanced surface plasmon resonance behavior, which can be readily tuned by EDRR and dealloying parameters. These results highlight the significant potential of the EDRR-dealloying route to produce different types of Ag/Zn alloys and optically functional materials directly frombase metal process solutions.",

keywords = "EDRR, Dendrite, Circular Economy, Crystal growth, Optical properties",

author = "Zulin Wang and Kirsi Yliniemi and Eeva-Leena Rautama and Pyry-Mikko Hannula and Wilson, {Benjamin P.} and Mari Lundstr{\"o}m",

note = "Academy of Finland project (GoldTail (319691) BW) and EARMetal (339979, ML, KY) are greatly acknowledged for funding this research. The RawMatTERS Finland Infrastructure (RAMI) funded by the Academy of Finland and based at Aalto University is also acknowledged. In addition, Zulin Wang would like to acknowledge the financial support from the Chinese Scholarship Council (CSC). The authors would also like to thank Min Chen for his valuable suggestion and discussion.",

year = "2022",

month = mar,

day = "21",

doi = "10.1021/acssuschemeng.2c00284",

language = "English",

volume = "10",

pages = "3716–3725",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior

AU - Wang, Zulin

AU - Yliniemi, Kirsi

AU - Rautama, Eeva-Leena

AU - Hannula, Pyry-Mikko

AU - Wilson, Benjamin P.

AU - Lundström, Mari

N1 - Academy of Finland project (GoldTail (319691) BW) and EARMetal (339979, ML, KY) are greatly acknowledged for funding this research. The RawMatTERS Finland Infrastructure (RAMI) funded by the Academy of Finland and based at Aalto University is also acknowledged. In addition, Zulin Wang would like to acknowledge the financial support from the Chinese Scholarship Council (CSC). The authors would also like to thank Min Chen for his valuable suggestion and discussion.

PY - 2022/3/21

Y1 - 2022/3/21

N2 - This study investigates the sustainable preparation of Ag/Zn alloys from a simulated zinc process solution (20 ppm Ag, 65 g/L Zn, and 10 g/L H2SO4) via electrodeposition-redox replacement (EDRR) and the electrochemical dealloying behavior of the Ag/Zn alloys. Results indicate that Ag/Zn deposits with diverse compositions and microstructures can be obtained at room temperature without any complexing agents, simply by varying EDRR parameters like deposition time,deposition potential, and redox replacement time. Two types of Ag/Zn intermetallics (Zn0.96Ag0.04 and Ag0.76Zn0.24) were identified by the combination of X-ray diffraction (XRD) and anodic linear sweep voltammetry. Mass-transfer limitations have significant effects on the growth process, and a nucleation-growth mechanism from Ag/Zn particles into dendrites with increased EDRR cycles is introduced: with EDRR parameters favoring mass-transfer limitations (higher overpotentials, longer deposition times, and shorter redox replacement times), a more dendritic morphology of Ag/Zn alloys is achieved. The selective dissolution of Zn (i.e. dealloying) allowed the formation of silver-rich surfaces with an enhanced surface plasmon resonance behavior, which can be readily tuned by EDRR and dealloying parameters. These results highlight the significant potential of the EDRR-dealloying route to produce different types of Ag/Zn alloys and optically functional materials directly frombase metal process solutions.

AB - This study investigates the sustainable preparation of Ag/Zn alloys from a simulated zinc process solution (20 ppm Ag, 65 g/L Zn, and 10 g/L H2SO4) via electrodeposition-redox replacement (EDRR) and the electrochemical dealloying behavior of the Ag/Zn alloys. Results indicate that Ag/Zn deposits with diverse compositions and microstructures can be obtained at room temperature without any complexing agents, simply by varying EDRR parameters like deposition time,deposition potential, and redox replacement time. Two types of Ag/Zn intermetallics (Zn0.96Ag0.04 and Ag0.76Zn0.24) were identified by the combination of X-ray diffraction (XRD) and anodic linear sweep voltammetry. Mass-transfer limitations have significant effects on the growth process, and a nucleation-growth mechanism from Ag/Zn particles into dendrites with increased EDRR cycles is introduced: with EDRR parameters favoring mass-transfer limitations (higher overpotentials, longer deposition times, and shorter redox replacement times), a more dendritic morphology of Ag/Zn alloys is achieved. The selective dissolution of Zn (i.e. dealloying) allowed the formation of silver-rich surfaces with an enhanced surface plasmon resonance behavior, which can be readily tuned by EDRR and dealloying parameters. These results highlight the significant potential of the EDRR-dealloying route to produce different types of Ag/Zn alloys and optically functional materials directly frombase metal process solutions.

KW - EDRR

KW - Dendrite

KW - Circular Economy

KW - Crystal growth

KW - Optical properties

UR - http://www.scopus.com/inward/record.url?scp=85126786601&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.2c00284

DO - 10.1021/acssuschemeng.2c00284

M3 - Article

SN - 2168-0485

VL - 10

SP - 3716

EP - 3725

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 11

ER -

Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior

Abstrakti

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Tietoaineistot

Dataset Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behavior

Projektit

EARMetal, Hydro: Electrochemically Assisted Aqueous Reduction of Waste Streams for Metals Recovery and Functional Surfaces

GoldTail: Kultapitoisten rikastushiekkojen kestävä hyödyntäminen (GoldTail)

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Raaka-aineiden tutkimusinfrastruktuuri

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