The contributions of deuterium molecular emission to the total deuterium radiation was assessed in DIII-D ohmically-confined plasmas in high-recycling divertor conditions. Radial profiles of the deuterium Ly-α line intensity across the low-field side divertor leg were obtained with the recently installed divertor Survey Poor Resolution, Extended Spectrometer . A high-resolution spectrometer was used to measure the poloidal profiles of the deuterium Balmer-α and the deuterium Fulcher-α band intensity in the visible wavelength range. The scrape-off layer plasma and neutral distributions were simulated using the edge fluid EDGE2D-EIRENE , and the numerical solutions constrained utilizing Thomson scattering and Langmuir probe measurements at the low-field side midplane and the divertor target plate. The studies show that for these conditions molecular emission plays a negligible role in the total radiative power balance of the low-field side divertor, but molecular processes are important when evaluating deuterium Balmer-α line intensity for code-experiment validation.