Direct CO2 capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures

Guillermo Reyes; Mabel Vega-Coloma; Anna Antonova; Rubina Ajdary; Solene Jonveaux; Colleen Flanigan; Nathalie Lautenbacher; Orlando J. Rojas

doi:10.1002/adma.202209327

Direct CO₂ capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures

Guillermo Reyes^*, Mabel Vega-Coloma, Anna Antonova, Rubina Ajdary, Solene Jonveaux, Colleen Flanigan, Nathalie Lautenbacher, Orlando J. Rojas^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

19 Sitaatiot (Scopus)

144 Lataukset (Pure)

Abstrakti

Current carbon capture and utilization (CCU) technologies require high energy input and costly catalysts. Here, an effective pathway is offered that addresses climate action by atmospheric CO₂ sequestration. Industrially relevant highly reactive alkali cellulose solutions are used as CO₂ absorption media. The latter lead to mineralized cellulose materials (MCM) at a tailorable cellulose-to-mineral ratio, forming organic-inorganic viscous systems (viscosity from 10² to 10⁷ mPa s and storage modulus from 10 to 10⁵ Pa). CO₂absorption and conversion into calcium carbonate and associated minerals translate to maximum absorption of 6.5 gCO₂ g_cellulose⁻¹, tracking inversely with cellulose loading. Cellulose lean gels are easily converted into dry powders, shown as a functional component of ceramic glazes and cementitious composites. Meanwhile, cellulose-rich gels are moldable and extrudable, yielding stone-like structures tested as artificial substrates for coral reef restoration. Life Cycle Assessment (LCA) suggests new CCU opportunities for building materials, as demonstrated in underwater deployment for coral reef ecosystem restoration.

Alkuperäiskieli	Englanti
Artikkeli	2209327
Sivumäärä	12
Julkaisu	Advanced Materials
Vuosikerta	35
Numero	11
Varhainen verkossa julkaisun päivämäärä	26 tammik. 2023
DOI - pysyväislinkit	https://doi.org/10.1002/adma.202209327
Tila	Julkaistu - 16 maalisk. 2023
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.1002/adma.202209327Lisenssi: CC BY

CHEM_Reyes_et_al_Direct_CO2_Capture_2023_Advanced_MaterialsFinal published version, 3,07 MBLisenssi: CC BY

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BioELCell: Bioproducts Engineered from Lignocelluloses: from plants and upcycling to next generation materials
Rojas Gaona, O. (Vastuullinen tutkija), Abidnejad, R. (Projektin jäsen), Ajdary, R. (Projektin jäsen), Bhattarai, M. (Projektin jäsen), Zhu, Y. (Projektin jäsen), Zhao, B. (Projektin jäsen), Robertson, D. (Projektin jäsen), Reyes Torres, G. (Projektin jäsen), Johansson, L.-S. (Projektin jäsen), Garcia Greca, L. (Projektin jäsen), Klockars, K. (Projektin jäsen), Kämäräinen, T. (Projektin jäsen), Majoinen, J. (Projektin jäsen), Tardy, B. (Projektin jäsen), Dufau Mattos, B. (Projektin jäsen) & Ressouche, E. (Projektin jäsen)
30/07/2018 → 31/07/2023
Projekti: EU: ERC grants
FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future
Mäkelä, K. (Vastuullinen tutkija)
01/05/2018 → 31/12/2022
Projekti: Academy of Finland: Other research funding

OtaNano
Rissanen, A. (Manager)
Aalto-yliopisto
Laitteistot/tilat: Facility
OtaNano Nanomikroskopiakeskus
Seitsonen, J. (Manager) & Rissanen, A. (Other)
OtaNano
Laitteistot/tilat: Facility

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@article{5228149e63e44d339ab7d48619d38f46,

title = "Direct CO2 capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures",

abstract = "Current carbon capture and utilization (CCU) technologies require high energy input and costly catalysts. Here, an effective pathway is offered that addresses climate action by atmospheric CO2 sequestration. Industrially relevant highly reactive alkali cellulose solutions are used as CO2 absorption media. The latter lead to mineralized cellulose materials (MCM) at a tailorable cellulose-to-mineral ratio, forming organic-inorganic viscous systems (viscosity from 102 to 107 mPa s and storage modulus from 10 to 105 Pa). CO2 absorption and conversion into calcium carbonate and associated minerals translate to maximum absorption of 6.5 gCO2 gcellulose−1, tracking inversely with cellulose loading. Cellulose lean gels are easily converted into dry powders, shown as a functional component of ceramic glazes and cementitious composites. Meanwhile, cellulose-rich gels are moldable and extrudable, yielding stone-like structures tested as artificial substrates for coral reef restoration. Life Cycle Assessment (LCA) suggests new CCU opportunities for building materials, as demonstrated in underwater deployment for coral reef ecosystem restoration.",

author = "Guillermo Reyes and Mabel Vega-Coloma and Anna Antonova and Rubina Ajdary and Solene Jonveaux and Colleen Flanigan and Nathalie Lautenbacher and Rojas, {Orlando J.}",

note = "The authors acknowledge the help and contribution of Dr. Donald Potts's laboratory at the University of California-Santa Cruz, Long Marine Laboratory. The authors also acknowledge the electrolytic coral restoration structure placed on the Cozumel coast (Mexico, August 8th to September 29th, 2021, Flanigan, C. Zoe a living sea sculpture. https://zoecoral.com/). G.R. and O.J.R. acknowledge the funding contribution of UPM and support of the Academy of Finland's Flagship Program under Projects Nos. 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). G.R., R.A., and O.J.R. are grateful for the support received from the ERC Advanced Grant Agreement No. 788489 (“BioElCell”), the Canada Excellence Research Chair Program (CERC-2018-00006), and Canada Foundation for Innovation (Project number 38623). Coral testing in Mexico was funded with Patreon funds from Chris Anderson to Living Sea Sculpture. G.R. and N.B. acknowledge the help and contribution of Tomi Pelkonen, Aalto University Ceramic Studio Technician. C.F. and S.J. acknowledge the help and contribution of Dr. Donald Potts's laboratory at the University of California- Santa Cruz, Long Marine Laboratory, and Dr. David Vaughan of Plant a Million Corals Foundation in Florida. Joey Mandara of The Brinton Environmental Center, Boy Scouts of America High Adventure Camp, is also gratefully acknowledged for his monitoring and photographs of the corals on the CS. M.V. is grateful for the support of the Research Group at Universidad del B{\'i}o-B{\'i}o (DYPCS-UBB 2110375 GI_EF). The provision of facilities and technical support by Aalto University at OtaNano – Nanomicroscopy Center (Aalto-NMC) is also gratefully acknowledged.",

year = "2023",

month = mar,

day = "16",

doi = "10.1002/adma.202209327",

language = "English",

volume = "35",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

number = "11",

}

TY - JOUR

T1 - Direct CO2 capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures

AU - Reyes, Guillermo

AU - Vega-Coloma, Mabel

AU - Antonova, Anna

AU - Ajdary, Rubina

AU - Jonveaux, Solene

AU - Flanigan, Colleen

AU - Lautenbacher, Nathalie

AU - Rojas, Orlando J.

N1 - The authors acknowledge the help and contribution of Dr. Donald Potts's laboratory at the University of California-Santa Cruz, Long Marine Laboratory. The authors also acknowledge the electrolytic coral restoration structure placed on the Cozumel coast (Mexico, August 8th to September 29th, 2021, Flanigan, C. Zoe a living sea sculpture. https://zoecoral.com/). G.R. and O.J.R. acknowledge the funding contribution of UPM and support of the Academy of Finland's Flagship Program under Projects Nos. 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). G.R., R.A., and O.J.R. are grateful for the support received from the ERC Advanced Grant Agreement No. 788489 (“BioElCell”), the Canada Excellence Research Chair Program (CERC-2018-00006), and Canada Foundation for Innovation (Project number 38623). Coral testing in Mexico was funded with Patreon funds from Chris Anderson to Living Sea Sculpture. G.R. and N.B. acknowledge the help and contribution of Tomi Pelkonen, Aalto University Ceramic Studio Technician. C.F. and S.J. acknowledge the help and contribution of Dr. Donald Potts's laboratory at the University of California- Santa Cruz, Long Marine Laboratory, and Dr. David Vaughan of Plant a Million Corals Foundation in Florida. Joey Mandara of The Brinton Environmental Center, Boy Scouts of America High Adventure Camp, is also gratefully acknowledged for his monitoring and photographs of the corals on the CS. M.V. is grateful for the support of the Research Group at Universidad del Bío-Bío (DYPCS-UBB 2110375 GI_EF). The provision of facilities and technical support by Aalto University at OtaNano – Nanomicroscopy Center (Aalto-NMC) is also gratefully acknowledged.

PY - 2023/3/16

Y1 - 2023/3/16

N2 - Current carbon capture and utilization (CCU) technologies require high energy input and costly catalysts. Here, an effective pathway is offered that addresses climate action by atmospheric CO2 sequestration. Industrially relevant highly reactive alkali cellulose solutions are used as CO2 absorption media. The latter lead to mineralized cellulose materials (MCM) at a tailorable cellulose-to-mineral ratio, forming organic-inorganic viscous systems (viscosity from 102 to 107 mPa s and storage modulus from 10 to 105 Pa). CO2 absorption and conversion into calcium carbonate and associated minerals translate to maximum absorption of 6.5 gCO2 gcellulose−1, tracking inversely with cellulose loading. Cellulose lean gels are easily converted into dry powders, shown as a functional component of ceramic glazes and cementitious composites. Meanwhile, cellulose-rich gels are moldable and extrudable, yielding stone-like structures tested as artificial substrates for coral reef restoration. Life Cycle Assessment (LCA) suggests new CCU opportunities for building materials, as demonstrated in underwater deployment for coral reef ecosystem restoration.

AB - Current carbon capture and utilization (CCU) technologies require high energy input and costly catalysts. Here, an effective pathway is offered that addresses climate action by atmospheric CO2 sequestration. Industrially relevant highly reactive alkali cellulose solutions are used as CO2 absorption media. The latter lead to mineralized cellulose materials (MCM) at a tailorable cellulose-to-mineral ratio, forming organic-inorganic viscous systems (viscosity from 102 to 107 mPa s and storage modulus from 10 to 105 Pa). CO2 absorption and conversion into calcium carbonate and associated minerals translate to maximum absorption of 6.5 gCO2 gcellulose−1, tracking inversely with cellulose loading. Cellulose lean gels are easily converted into dry powders, shown as a functional component of ceramic glazes and cementitious composites. Meanwhile, cellulose-rich gels are moldable and extrudable, yielding stone-like structures tested as artificial substrates for coral reef restoration. Life Cycle Assessment (LCA) suggests new CCU opportunities for building materials, as demonstrated in underwater deployment for coral reef ecosystem restoration.

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U2 - 10.1002/adma.202209327

DO - 10.1002/adma.202209327

M3 - Article

SN - 0935-9648

VL - 35

JO - Advanced Materials

JF - Advanced Materials

IS - 11

M1 - 2209327

ER -

Direct CO2 capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures

Abstrakti

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

BioELCell: Bioproducts Engineered from Lignocelluloses: from plants and upcycling to next generation materials

FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future

Laitteet

OtaNano

OtaNano Nanomikroskopiakeskus

Siteeraa tätä

Direct CO₂ capture by alkali-dissolved cellulose and sequestration in building materials and artificial reef structures