Decomposition behaviour of PbSO4 during lead acid battery paste recycling process

Yun Li, Chaobo Tang, Pekka Taskinen, Shenghai Yang, Yongming Chen , Ari Jokilaakso

Tutkimustuotos: Artikkeli kirjassa/konferenssijulkaisussaConference contributionScientificvertaisarvioitu

Abstrakti

This work summarizes shortly the current lead-acid battery (LAB) recycling technologies, and proposes a cleaner and environmentally friendly LABs recycling process: a reductive sulphur-fixing recycling method. The dissociation behaviour of PbSO4, the main component in lead paste, during this new recycling process was investigated in detail. The phase transformation mechanisms during PbSO4 dissociation at Ar and air atmosphere were detected, respectively, with the help of thermogravimetric analysis (TG-DTA) and X-ray diffraction analysis techniques. Moreover, the gaseous dissociation products were separated, collected and analyzed. The investigation revealed that PbSO4 decomposition degree and partial pressures of gaseous products (SO3and SO2) in Ar were higher than in air atmosphere. Furthermore, partial pressure of SO2, (Pso2) was, generally, higher than (Pso3). In other words, increase of temperature promoted the dissociation of PbSO4.
AlkuperäiskieliEnglanti
OtsikkoProceedings of the 10th European Metallurgical Conference, EMC 2019
JulkaisupaikkaClausthal-Zellerfeld
KustantajaGDMB Verlag GmbH
Sivut1037-1048
Sivumäärä12
Vuosikerta3
ISBN (painettu)978-3-940276-89-6
TilaJulkaistu - 2019
OKM-julkaisutyyppiA4 Artikkeli konferenssijulkaisuussa
TapahtumaEuropean Metallurgical Conference - Congress Center Düsseldorf Süd , Düsseldorf, Saksa
Kesto: 23 kesäkuuta 201926 kesäkuuta 2019
Konferenssinumero: 10
https://emc.gdmb.de

Conference

ConferenceEuropean Metallurgical Conference
LyhennettäEMC
MaaSaksa
KaupunkiDüsseldorf
Ajanjakso23/06/201926/06/2019
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