Chemical recycling of hemp waste textiles via the ionic liquid based dry-jet-wet spinning technology

Marja Rissanen*, Inge Schlapp-Hackl, Daisuke Sawada, Susanna Raiskio, Krishna Ojha, Edward Smith, Herbert Sixta*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

7 Sitaatiot (Scopus)
110 Lataukset (Pure)

Abstrakti

The chemical recycling of hemp fabric into high-tenacity man-made cellulose fibers was demonstrated. The fabric was laundered 25 and 50 times to mimic the wear cycles of post-consumer textile waste. Despite the launderings, the molar mass of the material was still too high for recycling via dry-jet-wet spinning. Thus, the fabrics were treated with an aqueous sulfuric acid solution to adjust the intrinsic viscosity to the targeted level of 400–500 ml/g. The acid hydrolyzed sample was dissolved in 1,5-diazabicyclo[4.3.0]non-5-enium acetate and man-made cellulose fibers were regenerated by dry-jet-wet spinning. The properties of hemp and regenerated fibers were determined by tensile testing, birefringence measurements, and X-ray diffraction. Regenerated fibers were spun into yarn and knitted into a fabric. The tensile properties of the yarn and the abrasion and pilling resistance of the fabric were determined. Regenerated fibers showed a higher modulus of toughness (55.9 MPa) compared with hemp fibers (28.7 MPa). The fineness and staple length uniformity of regenerated fibers resulted in a high yarn structure evenness, a yarn tenacity of 28.1 cN/tex, and an elongation at break of 7.5%. Due to the even fabric structure, the fabric from regenerated fibers showed higher abrasion resistance than the hemp fabric.
AlkuperäiskieliEnglanti
Sivut2545-2557
Sivumäärä13
JulkaisuTextile Research Journal
Vuosikerta93
Numero11-12
Varhainen verkossa julkaisun päivämäärä18 jouluk. 2022
DOI - pysyväislinkit
TilaJulkaistu - kesäk. 2023
OKM-julkaisutyyppiA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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