Chemical Recovery of γ-Valerolactone/Water Biorefinery

Huy Quang Lê, Juha Pekka Pokki, Marc Borrega, Petri Uusi-Kyyny, Ville Alopaeus, Herbert Sixta*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

6 Sitaatiot (Scopus)
133 Lataukset (Pure)

Abstrakti

We introduce the optimization of the pulping conditions and propose different chemical recovery options for a proven biorefinery concept based on γ-valerolactone (GVL)/water fractionation. The pulping process has been optimized whereby the liquor-to-wood (L:W) ratio could be reduced to 3 L/kg without compromising the pulp properties as raw material for textile fibers production. The recovery of the pulping solvent was performed through combinations of lignin precipitation by water addition, distillation at reduced pressure, and liquid CO2 extraction. With a two-step lignin precipitation coupled with vacuum distillation, more than 90% of lignin and GVL could be recovered from the spent liquor. However, a significant part of GVL remained unrecoverable in the residue, which was a highly viscous liquid with complicated phase behavior. The recovery by lignin precipitation combined with liquid CO2 extraction could recover more than 85% GVL and 90% lignin without forming any problematic residue as in the distillation process. The remaining GVL remained in the raffinate containing a low amount of lignin and other compounds, which can be further processed to isolate the GVL and improve the recovery rate.

AlkuperäiskieliEnglanti
Sivut15147-15158
Sivumäärä12
JulkaisuIndustrial and Engineering Chemistry Research
Vuosikerta57
Numero44
DOI - pysyväislinkit
TilaJulkaistu - 7 marraskuuta 2018
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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  • Projektit

    CERES Mod1 GVL-REC

    Sixta, H., Le, H. Q. & Granatier, M.

    01/05/201831/12/2022

    Projekti: Academy of Finland: Other research funding

    CERES: Competence Center for the materials Bioeconomy: A Flagship for our Sustainable Future

    Mäkelä, K.

    01/05/201831/12/2022

    Projekti: Academy of Finland: Other research funding

    Laitteet

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