Chemical characterization of hydrothermally pretreated and enzyme-digested wheat straw: An evaluation of recalcitrance

Zara Merali, Kaisa Marjamaa, Andres Käsper, Kristiina Kruus, A. Patrick Gunning, Vic J. Morris, Keith W. Waldron*

*Tämän työn vastaava kirjoittaja

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

12 Sitaatiot (Scopus)

Abstrakti

There is great interest in understanding changes that occur to cell wall constituents during saccharification of pretreated lignocellulose, particularly in relation to recalcitrance of the residues. This paper reports the effects of hydrothermal pretreatment followed by enzyme hydrolysis on the extractability and properties of recalcitrant wheat straw polymers. The results show that the undigested residue had lost much of its archestructure. Compositional analysis portrayed a considerable loss of cross-linking di-ferulic acid phenolics, hemicellulosic and cellulosic sugars. The remaining cellulosic and non-cellulosic polysaccharides were much more readily extractable in alkali and molecular profiling revealed the presence of low Mw oligomers in the fractions suggesting the partial enzyme hydrolysis of hemicelluloses and cellulose. Simultaneous saccharification and fermentation of the pretreated and enzyme-digested residues surprisingly resulted in ethanol yields of up to 99% of the theoretical. This is discussed in relation to the "recalcitrant" nature of the original pretreated and enzyme digested biomass.

AlkuperäiskieliEnglanti
Sivut132-140
Sivumäärä9
JulkaisuFOOD CHEMISTRY
Vuosikerta198
DOI - pysyväislinkit
TilaJulkaistu - 1 toukokuuta 2016
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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