Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 – Manufacturing and properties of precursor fibres

Mikaela Trogen; Nguyen Duc Le; Daisuke Sawada; Chamseddine Guizani; Tainise Vergara Lourençon; Leena Pitkänen; Herbert Sixta; Riddhi Shah; Hugh O'Neill; Mikhail Balakshin; Nolene Byrne; Michael Hummel

doi:10.1016/j.carbpol.2020.117133

Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 – Manufacturing and properties of precursor fibres

Mikaela Trogen
, Nguyen Duc Le
, Daisuke Sawada
, Chamseddine Guizani
, Tainise Vergara Lourençon
, Leena Pitkänen
, Herbert Sixta
, Riddhi Shah
, Hugh O'Neill
, Mikhail Balakshin
, Nolene Byrne
, Michael Hummel^*

^*Tämän työn vastaava kirjoittaja

Deakin University
Oak Ridge Natl Lab, Oak Ridge National Laboratory, United States Department of Energy (DOE)

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

61 Sitaatiot (Scopus)

364 Lataukset (Pure)

Abstrakti

Cellulose-lignin composite fibres were spun from ionic liquid (IL) solutions by dry-jet wet spinning. Birch pre-hydrolysed Kraft (PHK) pulp and organosolv beech (BL) or spruce lignin (SL) were dissolved in the IL 1,5-diazabicyclo[4.3.0]non-5-enium acetate ([DBNH]OAc) to prepare spinning dopes. Fibres with lignin concentrations of up to 50 % were spun successfully. The fibres were analysed focusing on important properties for the production of carbon fibres (CF). Due to the higher molar mass of the SL compared to the BL, SL showed higher stability in the spinning process, giving higher lignin content in the final fibres. The CF yield after carbonization increased with increasing lignin content. The higher carbon content of SL compared to BL, resulted in moderately higher CF yield of the SL fibres, compared to fibres with BL. Overall, the produced cellulose-lignin composite fibres show great potential as precursors for CF production.

Alkuperäiskieli	Englanti
Artikkeli	117133
Sivumäärä	10
Julkaisu	Carbohydrate Polymers
Vuosikerta	252
DOI - pysyväislinkit	https://doi.org/10.1016/j.carbpol.2020.117133
Tila	Julkaistu - 15 tammik. 2021
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Rahoitus

This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (Grant Agreement No 715788 ). The authors thank the European Synchrotron Radiation Facility (ESRF) for the provision of beam time at the D2AM beamline.

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10.1016/j.carbpol.2020.117133

CHEM_Trogen_et_al_Cellulose_lignin_composite_fibres_part_1_Carbohydrate_PolymersAccepted author manuscript, 632 KBLisenssi: CC BY-NC-ND

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1 Päättynyt

WoCaFi: Unlocking the Entire Wood Matrix for the Next Generation of Carbon Fibers
Hummel, M. (Vastuullinen johtaja), Revitzer, H. (Projektin jäsen), Selinger, J. (Projektin jäsen), Trogen, M. (Projektin jäsen), Fliri, L. (Projektin jäsen), Zahra, H. (Projektin jäsen), Li, O. (Projektin jäsen), Miranda Valdez, I. (Projektin jäsen), Johansson, L.-S. (Projektin jäsen), Langhans, M. (Projektin jäsen) & Sawada, D. (Projektin jäsen)
01/01/2017 → 31/03/2022
Projekti: EU: ERC grants

Siteeraa tätä

Trogen, M., Le, N. D., Sawada, D., Guizani, C., Lourençon, T. V., Pitkänen, L., Sixta, H., Shah, R., O'Neill, H., Balakshin, M., Byrne, N., & Hummel, M. (2021). Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 – Manufacturing and properties of precursor fibres. Carbohydrate Polymers, 252, Artikkeli 117133. https://doi.org/10.1016/j.carbpol.2020.117133

@article{29d7e4930a454119860738ae9dccac67,

title = "Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 {\textendash} Manufacturing and properties of precursor fibres",

abstract = "Cellulose-lignin composite fibres were spun from ionic liquid (IL) solutions by dry-jet wet spinning. Birch pre-hydrolysed Kraft (PHK) pulp and organosolv beech (BL) or spruce lignin (SL) were dissolved in the IL 1,5-diazabicyclo[4.3.0]non-5-enium acetate ([DBNH]OAc) to prepare spinning dopes. Fibres with lignin concentrations of up to 50 \% were spun successfully. The fibres were analysed focusing on important properties for the production of carbon fibres (CF). Due to the higher molar mass of the SL compared to the BL, SL showed higher stability in the spinning process, giving higher lignin content in the final fibres. The CF yield after carbonization increased with increasing lignin content. The higher carbon content of SL compared to BL, resulted in moderately higher CF yield of the SL fibres, compared to fibres with BL. Overall, the produced cellulose-lignin composite fibres show great potential as precursors for CF production.",

keywords = "Carbon fibres, Fibres, Ionic liquid, Precursor, Spinning",

author = "Mikaela Trogen and Le, \{Nguyen Duc\} and Daisuke Sawada and Chamseddine Guizani and Louren{\c c}on, \{Tainise Vergara\} and Leena Pitk{\"a}nen and Herbert Sixta and Riddhi Shah and Hugh O'Neill and Mikhail Balakshin and Nolene Byrne and Michael Hummel",

note = "| openaire: EC/H2020/715788/EU//WoCaFi",

year = "2021",

month = jan,

day = "15",

doi = "10.1016/j.carbpol.2020.117133",

language = "English",

volume = "252",

journal = "Carbohydrate Polymers",

issn = "0144-8617",

publisher = "Elsevier",

}

TY - JOUR

T1 - Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 – Manufacturing and properties of precursor fibres

AU - Trogen, Mikaela

AU - Le, Nguyen Duc

AU - Sawada, Daisuke

AU - Guizani, Chamseddine

AU - Lourençon, Tainise Vergara

AU - Pitkänen, Leena

AU - Sixta, Herbert

AU - Shah, Riddhi

AU - O'Neill, Hugh

AU - Balakshin, Mikhail

AU - Byrne, Nolene

AU - Hummel, Michael

N1 - | openaire: EC/H2020/715788/EU//WoCaFi

PY - 2021/1/15

Y1 - 2021/1/15

N2 - Cellulose-lignin composite fibres were spun from ionic liquid (IL) solutions by dry-jet wet spinning. Birch pre-hydrolysed Kraft (PHK) pulp and organosolv beech (BL) or spruce lignin (SL) were dissolved in the IL 1,5-diazabicyclo[4.3.0]non-5-enium acetate ([DBNH]OAc) to prepare spinning dopes. Fibres with lignin concentrations of up to 50 % were spun successfully. The fibres were analysed focusing on important properties for the production of carbon fibres (CF). Due to the higher molar mass of the SL compared to the BL, SL showed higher stability in the spinning process, giving higher lignin content in the final fibres. The CF yield after carbonization increased with increasing lignin content. The higher carbon content of SL compared to BL, resulted in moderately higher CF yield of the SL fibres, compared to fibres with BL. Overall, the produced cellulose-lignin composite fibres show great potential as precursors for CF production.

AB - Cellulose-lignin composite fibres were spun from ionic liquid (IL) solutions by dry-jet wet spinning. Birch pre-hydrolysed Kraft (PHK) pulp and organosolv beech (BL) or spruce lignin (SL) were dissolved in the IL 1,5-diazabicyclo[4.3.0]non-5-enium acetate ([DBNH]OAc) to prepare spinning dopes. Fibres with lignin concentrations of up to 50 % were spun successfully. The fibres were analysed focusing on important properties for the production of carbon fibres (CF). Due to the higher molar mass of the SL compared to the BL, SL showed higher stability in the spinning process, giving higher lignin content in the final fibres. The CF yield after carbonization increased with increasing lignin content. The higher carbon content of SL compared to BL, resulted in moderately higher CF yield of the SL fibres, compared to fibres with BL. Overall, the produced cellulose-lignin composite fibres show great potential as precursors for CF production.

KW - Carbon fibres

KW - Fibres

KW - Ionic liquid

KW - Precursor

KW - Spinning

UR - https://www.scopus.com/pages/publications/85092227576

U2 - 10.1016/j.carbpol.2020.117133

DO - 10.1016/j.carbpol.2020.117133

M3 - Article

AN - SCOPUS:85092227576

SN - 0144-8617

VL - 252

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

M1 - 117133

ER -

Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1 – Manufacturing and properties of precursor fibres

Abstrakti

Rahoitus

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

WoCaFi: Unlocking the Entire Wood Matrix for the Next Generation of Carbon Fibers

Siteeraa tätä