Catalytic Oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen

Thomas Straub; Ari Koskinen

doi:10.1016/S1387-7003(02)00644-5

Catalytic Oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen

Thomas Straub
, Ari Koskinen

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

21 Sitaatiot (Scopus)

333 Lataukset (Pure)

Abstrakti

The novel complex IndðCOÞ3Mo–RuðCOÞ2Cp (1) (Ind ¼ g5-indenyl; Cp ¼ g5-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards c-butyrolactone of up to 70% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone.

Alkuperäiskieli	Englanti
Sivut	1052-1055
Julkaisu	Inorganic Chemistry Communications
Vuosikerta	5
Numero	12
DOI - pysyväislinkit	https://doi.org/10.1016/S1387-7003(02)00644-5
Tila	Julkaistu - 2002
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Tutkimusalat

catalytic oxidation, cyclic ether, hetero dinuclear, organometallic

Pääsy asiakirjaan

10.1016/S1387-7003(02)00644-5

ms092Accepted author manuscript, 95,2 KB

Siteeraa tätä

@article{0f8cb30c77ea402bb7c422872ff0446c,

title = "Catalytic Oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen",

abstract = "The novel complex Ind{\dh}CO{\TH}3Mo–Ru{\dh}CO{\TH}2Cp (1) (Ind ¼ g5-indenyl; Cp ¼ g5-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards c-butyrolactone of up to 70\% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone.",

keywords = "catalytic oxidation, cyclic ether, hetero dinuclear, organometallic, catalytic oxidation, cyclic ether, hetero dinuclear, organometallic, catalytic aerobic oxidation, hetero bimetallic, molybdenum, ruthenium complex, cyclic ether",

author = "Thomas Straub and Ari Koskinen",

year = "2002",

doi = "10.1016/S1387-7003(02)00644-5",

language = "English",

volume = "5",

pages = "1052--1055",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "12",

}

TY - JOUR

T1 - Catalytic Oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen

AU - Straub, Thomas

AU - Koskinen, Ari

PY - 2002

Y1 - 2002

N2 - The novel complex IndðCOÞ3Mo–RuðCOÞ2Cp (1) (Ind ¼ g5-indenyl; Cp ¼ g5-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards c-butyrolactone of up to 70% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone.

AB - The novel complex IndðCOÞ3Mo–RuðCOÞ2Cp (1) (Ind ¼ g5-indenyl; Cp ¼ g5-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards c-butyrolactone of up to 70% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone.

KW - catalytic oxidation, cyclic ether, hetero dinuclear, organometallic

KW - catalytic aerobic oxidation

KW - hetero bimetallic

KW - molybdenum

KW - ruthenium complex

KW - cyclic ether

U2 - 10.1016/S1387-7003(02)00644-5

DO - 10.1016/S1387-7003(02)00644-5

M3 - Article

SN - 1387-7003

VL - 5

SP - 1052

EP - 1055

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Catalytic Oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen

Abstrakti

Tutkimusalat

Pääsy asiakirjaan

Sormenjälki

Siteeraa tätä