Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions

Shaochen Zhou; Bo Peng; Yanyan Duan; Kai Liu; Olli Ikkala; Robin H.A. Ras

doi:10.1002/anie.202210808

Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions

Shaochen Zhou
, Bo Peng^*
, Yanyan Duan
, Kai Liu
, Olli Ikkala
, Robin H.A. Ras

^*Tämän työn vastaava kirjoittaja

The IMDEA Materials Institute

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

21 Sitaatiot (Scopus)

107 Lataukset (Pure)

Abstrakti

Fluorescent supraparticles of gold, silver and copper nanoclusters are synthesized by simply drying of invert emulsions, resulting in a dozen-fold increase in photoluminescence quantum yield (up to ≈80 %) and a significant improvement in photostability. The inhibition of the ligand twisting during the intramolecular charge transfer is found to be responsible for the enhancement, especially for the gold nanocluster supraparticles. This research provides a general, flexible, and easy method for producing highly luminescent and photostable metal nanocluster-based materials that promise practical applications in white-light-emitting diodes.

Alkuperäiskieli	Englanti
Artikkeli	e202210808
Sivumäärä	6
Julkaisu	Angewandte Chemie - International Edition
Vuosikerta	61
Numero	40
Varhainen verkossa julkaisun päivämäärä	31 elok. 2022
DOI - pysyväislinkit	https://doi.org/10.1002/anie.202210808
Tila	Julkaistu - 4 lokak. 2022
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Rahoitus

Dr. Hua Jiang is acknowledged for his assistance in TEM characterization. This work was supported by ERC (Advanced Grant DRIVEN, No. 742829), the Academy of Finland (No. 310799, 321443, 13332370 and 328942). This work was carried out under the Academy of Finland Center of Excellence Program (2022–2029) in Life‐Inspired Hybrid Materials (LIBER) (project numbers 346108 and 346109). The facilities and technical support provided by Aalto University Nanomicroscopy Center (Aalto‐NMC), and computing time from CSC‐IT Center for Science are gratefully acknowledged.

Pääsy asiakirjaan

10.1002/anie.202210808Lisenssi: CC BY

Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert EmulsionsFinal published version, 762 KBLisenssi: CC BY

Muut tiedostot ja linkit

Linkki julkaisuun Scopuksessa

-: LIBER/Ras
Ras, R. (Vastuullinen johtaja), Morais Jaques, Y. (Projektin jäsen), Lepikko, S. (Projektin jäsen), Nurmi, H. (Projektin jäsen), Junaid, M. (Projektin jäsen), Liu, K. (Projektin jäsen), Huhtamäki, T. (Projektin jäsen), Wagener, L. Z. J. S. (Projektin jäsen), Zhou, S. (Projektin jäsen), Al-Terke, H. (Projektin jäsen), Vuckovac, M. (Projektin jäsen), Afzalifar, A. (Projektin jäsen) & Mattila, M. (Projektin jäsen)
01/01/2022 → 31/12/2024
Projekti: RCF Academy Project
-: LIBER/Ikkala
Ikkala, O. (Vastuullinen johtaja), Pi, H. (Projektin jäsen), Chandra, S. (Projektin jäsen), Kang, J. (Projektin jäsen), Liang, C. (Projektin jäsen), Gustavsson, L. (Projektin jäsen), Lin, Z. (Projektin jäsen), Hong, X. (Projektin jäsen), Fang, Y. (Projektin jäsen), Sheng, J. (Projektin jäsen) & Miao, Z. (Projektin jäsen)
01/01/2022 → 31/12/2024
Projekti: RCF Academy Project
Self-construction superhydrophobic surfaces
Liu, K. (Vastuullinen johtaja)
01/09/2020 → 31/08/2023
Projekti: RCF Postdoctoral Researcher

OtaNano
Rissanen, A. (Manager)
Aalto-yliopisto
Laitteistot/tilat: Facility
OtaNano Nanomikroskopiakeskus
Seitsonen, J. (Manager) & Rissanen, A. (Other)
OtaNano
Laitteistot/tilat: Facility

Siteeraa tätä

@article{e03693f4359b439ba153c7f552c6e5b1,

title = "Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions",

abstract = "Fluorescent supraparticles of gold, silver and copper nanoclusters are synthesized by simply drying of invert emulsions, resulting in a dozen-fold increase in photoluminescence quantum yield (up to ≈80 \%) and a significant improvement in photostability. The inhibition of the ligand twisting during the intramolecular charge transfer is found to be responsible for the enhancement, especially for the gold nanocluster supraparticles. This research provides a general, flexible, and easy method for producing highly luminescent and photostable metal nanocluster-based materials that promise practical applications in white-light-emitting diodes.",

keywords = "Light-Emitting Diode, Metal Nanoclusters, Photoluminescence, Photostability, Supraparticles",

author = "Shaochen Zhou and Bo Peng and Yanyan Duan and Kai Liu and Olli Ikkala and Ras, \{Robin H.A.\}",

note = "| openaire: EC/H2020/742829/EU//DRIVEN Funding Information: Dr. Hua Jiang is acknowledged for his assistance in TEM characterization. This work was supported by ERC (Advanced Grant DRIVEN, No. 742829), the Academy of Finland (No. 310799, 321443, 13332370 and 328942). This work was carried out under the Academy of Finland Center of Excellence Program (2022–2029) in Life‐Inspired Hybrid Materials (LIBER) (project numbers 346108 and 346109). The facilities and technical support provided by Aalto University Nanomicroscopy Center (Aalto‐NMC), and computing time from CSC‐IT Center for Science are gratefully acknowledged. Publisher Copyright: {\textcopyright} 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.",

year = "2022",

month = oct,

day = "4",

doi = "10.1002/anie.202210808",

language = "English",

volume = "61",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley",

number = "40",

}

TY - JOUR

T1 - Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions

AU - Zhou, Shaochen

AU - Peng, Bo

AU - Duan, Yanyan

AU - Liu, Kai

AU - Ikkala, Olli

AU - Ras, Robin H.A.

N1 - | openaire: EC/H2020/742829/EU//DRIVEN Funding Information: Dr. Hua Jiang is acknowledged for his assistance in TEM characterization. This work was supported by ERC (Advanced Grant DRIVEN, No. 742829), the Academy of Finland (No. 310799, 321443, 13332370 and 328942). This work was carried out under the Academy of Finland Center of Excellence Program (2022–2029) in Life‐Inspired Hybrid Materials (LIBER) (project numbers 346108 and 346109). The facilities and technical support provided by Aalto University Nanomicroscopy Center (Aalto‐NMC), and computing time from CSC‐IT Center for Science are gratefully acknowledged. Publisher Copyright: © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

PY - 2022/10/4

Y1 - 2022/10/4

N2 - Fluorescent supraparticles of gold, silver and copper nanoclusters are synthesized by simply drying of invert emulsions, resulting in a dozen-fold increase in photoluminescence quantum yield (up to ≈80 %) and a significant improvement in photostability. The inhibition of the ligand twisting during the intramolecular charge transfer is found to be responsible for the enhancement, especially for the gold nanocluster supraparticles. This research provides a general, flexible, and easy method for producing highly luminescent and photostable metal nanocluster-based materials that promise practical applications in white-light-emitting diodes.

AB - Fluorescent supraparticles of gold, silver and copper nanoclusters are synthesized by simply drying of invert emulsions, resulting in a dozen-fold increase in photoluminescence quantum yield (up to ≈80 %) and a significant improvement in photostability. The inhibition of the ligand twisting during the intramolecular charge transfer is found to be responsible for the enhancement, especially for the gold nanocluster supraparticles. This research provides a general, flexible, and easy method for producing highly luminescent and photostable metal nanocluster-based materials that promise practical applications in white-light-emitting diodes.

KW - Light-Emitting Diode

KW - Metal Nanoclusters

KW - Photoluminescence

KW - Photostability

KW - Supraparticles

UR - https://www.scopus.com/pages/publications/85137258301

U2 - 10.1002/anie.202210808

DO - 10.1002/anie.202210808

M3 - Article

AN - SCOPUS:85137258301

SN - 1433-7851

VL - 61

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

M1 - e202210808

ER -

Bright and Photostable Fluorescent Metal Nanocluster Supraparticles from Invert Emulsions

Abstrakti

Rahoitus

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

-: LIBER/Ras

-: LIBER/Ikkala

Self-construction superhydrophobic surfaces

Laitteet

OtaNano

OtaNano Nanomikroskopiakeskus

Siteeraa tätä