Abstrakti
The binary lead fluoride Pb3F8 was synthesized by the reaction of anhydrous HF with Pb3O4 or by the reaction of BrF3 with PbF2. The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS 19F NMR spectroscopy, as well as thermogravimetric analysis, XP and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Solid-state quantum-chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound.
Alkuperäiskieli | Englanti |
---|---|
Sivut | 15656-15661 |
Sivumäärä | 6 |
Julkaisu | Chemistry: A European Journal |
Vuosikerta | 25 |
Numero | 68 |
Varhainen verkossa julkaisun päivämäärä | 2019 |
DOI - pysyväislinkit | |
Tila | Julkaistu - 5 jouluk. 2019 |
OKM-julkaisutyyppi | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä |