Atomic-Scale Deformations at the Interface of a Mixed-Dimensional van der Waals Heterostructure

Kimmo Aleksi Mustonen, Aqeel Hussain, Christoph Hofer, Mohammad Reza Ahmadpour Monazam, Rasim Mirzayev, Kenan Elibol, Patrik Laiho, Clemens Mangler, Hua Jiang, Toma Susi, Esko I. Kauppinen, Jani Kotakoski, Jannik C. Meyer

Tutkimustuotos: LehtiartikkeliArticleScientificvertaisarvioitu

4 Sitaatiot (Scopus)
143 Lataukset (Pure)

Abstrakti

Molecular self-assembly due to chemical interactions is the basis of bottom-up nanofabrication, whereas weaker intermolecular forces dominate on the scale of macromolecules. Recent advances in synthesis and characterization have brought increasing attention to two- and mixed-dimensional heterostructures and it has been recognized that van der Waals (vdW) forces within the structure may have a significant impact on their morphology. Here, we suspend single-walled carbon nanotubes (SWCNTs) on graphene to create a model system for the study of a 1D-2D molecular interface through atomic resolution scanning transmission electron microscopy observations. When brought in contact, we observe radial deformation of SWCNTs and the emergence of long-range linear grooves in graphene revealed by three-dimensional reconstruction of the heterostructure. These topographic features are strain-correlated but show no sensitivity to carbon nanotube helicity, electronic structure, or stacking order. Finally, despite random deposition of the nanotubes, we show that the competition between strain and vdW forces results in aligned carbon-carbon interfaces spanning hundreds of nanometers.

AlkuperäiskieliEnglanti
Artikkeli8
Sivut8512–8519
JulkaisuACS Nano
Vuosikerta12
DOI - pysyväislinkit
TilaJulkaistu - 17 heinäkuuta 2018
OKM-julkaisutyyppiA1 Julkaistu artikkeli, soviteltu

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  • Projektit

    • 4 Päättynyt

    FEDOC / Kauppinen

    Raula, J., Liao, Y., Zhang, Q., Kauppinen, E., Khan, S. A. & Laiho, P.

    01/06/201630/06/2019

    Projekti: Business Finland: Other research funding

    CNT-PV: CNT-PV

    Wei, N., Kauppinen, E. & Zhang, Q.

    01/01/201630/04/2018

    Projekti: Business Finland: Other research funding

    Kestävän kehityksen mukaiset platinaryhmän metalleja sisältämättömät katalyytit

    Liao, Y., Kauppinen, E. & Khan, S. A.

    01/09/201524/09/2019

    Projekti: Academy of Finland: Other research funding

    Siteeraa tätä

    Mustonen, K. A., Hussain, A., Hofer, C., Reza Ahmadpour Monazam, M., Mirzayev, R., Elibol, K., ... Meyer, J. C. (2018). Atomic-Scale Deformations at the Interface of a Mixed-Dimensional van der Waals Heterostructure. ACS Nano, 12, 8512–8519. [8]. https://doi.org/10.1021/acsnano.8b04050