Aqueous-phase reforming of bio-oil aqueous fraction over nickel-based catalysts

Aitor Arandia; Irene Coronado; Aingeru Remiro; Ana G. Gayubo; Matti Reinikainen

doi:10.1016/j.ijhydene.2019.04.007

Aqueous-phase reforming of bio-oil aqueous fraction over nickel-based catalysts

Aitor Arandia^*, Irene Coronado, Aingeru Remiro, Ana G. Gayubo, Matti Reinikainen

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

44 Sitaatiot (Scopus)

Abstrakti

Aqueous-phase reforming (APR)is a quite new technology for the production of hydrogen and light hydrocarbons from aqueous-organic mixtures in a single-stage process. This manuscript analyzes the APR of representative model compounds of bio-oil aqueous fraction, including acetic acid, ethanol, 1-hydroxypropan-2-one (acetol)and benzene-1,2-diol (catechol), as well as a mixture of all of them. The APR experiments were conducted at 230 °C and 3.2 MPa over three different Ni-based catalysts, including spinel NiAl ₂ O ₄ , and supported Ni/CeO ₂ -γAl ₂ O ₃ and Ni/La ₂ O ₃ -αAl ₂ O ₃ . The reactivity of the model compounds varied largely in the order: acetol > ethanol > catechol > acetic acid, whereas the H ₂ production decreased in the following order: ethanol ≫> acetol > acetic acid > catechol. Based on the product distribution obtained, the reaction pathways in the APR of each model compound have been proposed. In the APR of the mixture, the Ni/La ₂ O ₃ -αAl ₂ O ₃ led to the highest H ₂ yield but was affected by Ni leaching, whereas spinel NiAl ₂ O ₄ showed a much higher stability. Therefore, the Ni-spinel catalyst showed a good potential for H ₂ production by APR of bio-oil aqueous fraction.

Alkuperäiskieli	Englanti
Sivut	13157-13168
Sivumäärä	12
Julkaisu	International Journal of Hydrogen Energy
Vuosikerta	44
Numero	26
DOI - pysyväislinkit	https://doi.org/10.1016/j.ijhydene.2019.04.007
Tila	Julkaistu - 21 toukok. 2019
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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10.1016/j.ijhydene.2019.04.007

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Biojalostamon vesivirtojen katalyyttinen vesifaasireformointi
Rinta-Paavola, A. (Projektin jäsen), Arandia Gutierrez, A. (Projektin jäsen), Karinen, R. (Vastuullinen tutkija), Harju, H. (Projektin jäsen), Stekrova, M. (Projektin jäsen), Lehtonen, J. (Projektin jäsen), Puurunen, R. (Projektin jäsen), Mäkelä, E. (Projektin jäsen) & Khan, Y. (Projektin jäsen)
01/01/2015 → 31/12/2018
Projekti: Academy of Finland: Other research funding

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@article{c071d89d2f5d4e589f56311987229ab7,

title = "Aqueous-phase reforming of bio-oil aqueous fraction over nickel-based catalysts",

abstract = " Aqueous-phase reforming (APR)is a quite new technology for the production of hydrogen and light hydrocarbons from aqueous-organic mixtures in a single-stage process. This manuscript analyzes the APR of representative model compounds of bio-oil aqueous fraction, including acetic acid, ethanol, 1-hydroxypropan-2-one (acetol)and benzene-1,2-diol (catechol), as well as a mixture of all of them. The APR experiments were conducted at 230 °C and 3.2 MPa over three different Ni-based catalysts, including spinel NiAl 2 O 4 , and supported Ni/CeO 2 -γAl 2 O 3 and Ni/La 2 O 3 -αAl 2 O 3 . The reactivity of the model compounds varied largely in the order: acetol > ethanol > catechol > acetic acid, whereas the H 2 production decreased in the following order: ethanol ≫> acetol > acetic acid > catechol. Based on the product distribution obtained, the reaction pathways in the APR of each model compound have been proposed. In the APR of the mixture, the Ni/La 2 O 3 -αAl 2 O 3 led to the highest H 2 yield but was affected by Ni leaching, whereas spinel NiAl 2 O 4 showed a much higher stability. Therefore, the Ni-spinel catalyst showed a good potential for H 2 production by APR of bio-oil aqueous fraction. ",

keywords = "Aqueous-phase reforming, Bio-oil, Hydrogen, Ni-based catalysts",

author = "Aitor Arandia and Irene Coronado and Aingeru Remiro and Gayubo, {Ana G.} and Matti Reinikainen",

year = "2019",

month = may,

day = "21",

doi = "10.1016/j.ijhydene.2019.04.007",

language = "English",

volume = "44",

pages = "13157--13168",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier",

number = "26",

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TY - JOUR

T1 - Aqueous-phase reforming of bio-oil aqueous fraction over nickel-based catalysts

AU - Arandia, Aitor

AU - Coronado, Irene

AU - Remiro, Aingeru

AU - Gayubo, Ana G.

AU - Reinikainen, Matti

PY - 2019/5/21

Y1 - 2019/5/21

N2 - Aqueous-phase reforming (APR)is a quite new technology for the production of hydrogen and light hydrocarbons from aqueous-organic mixtures in a single-stage process. This manuscript analyzes the APR of representative model compounds of bio-oil aqueous fraction, including acetic acid, ethanol, 1-hydroxypropan-2-one (acetol)and benzene-1,2-diol (catechol), as well as a mixture of all of them. The APR experiments were conducted at 230 °C and 3.2 MPa over three different Ni-based catalysts, including spinel NiAl 2 O 4 , and supported Ni/CeO 2 -γAl 2 O 3 and Ni/La 2 O 3 -αAl 2 O 3 . The reactivity of the model compounds varied largely in the order: acetol > ethanol > catechol > acetic acid, whereas the H 2 production decreased in the following order: ethanol ≫> acetol > acetic acid > catechol. Based on the product distribution obtained, the reaction pathways in the APR of each model compound have been proposed. In the APR of the mixture, the Ni/La 2 O 3 -αAl 2 O 3 led to the highest H 2 yield but was affected by Ni leaching, whereas spinel NiAl 2 O 4 showed a much higher stability. Therefore, the Ni-spinel catalyst showed a good potential for H 2 production by APR of bio-oil aqueous fraction.

AB - Aqueous-phase reforming (APR)is a quite new technology for the production of hydrogen and light hydrocarbons from aqueous-organic mixtures in a single-stage process. This manuscript analyzes the APR of representative model compounds of bio-oil aqueous fraction, including acetic acid, ethanol, 1-hydroxypropan-2-one (acetol)and benzene-1,2-diol (catechol), as well as a mixture of all of them. The APR experiments were conducted at 230 °C and 3.2 MPa over three different Ni-based catalysts, including spinel NiAl 2 O 4 , and supported Ni/CeO 2 -γAl 2 O 3 and Ni/La 2 O 3 -αAl 2 O 3 . The reactivity of the model compounds varied largely in the order: acetol > ethanol > catechol > acetic acid, whereas the H 2 production decreased in the following order: ethanol ≫> acetol > acetic acid > catechol. Based on the product distribution obtained, the reaction pathways in the APR of each model compound have been proposed. In the APR of the mixture, the Ni/La 2 O 3 -αAl 2 O 3 led to the highest H 2 yield but was affected by Ni leaching, whereas spinel NiAl 2 O 4 showed a much higher stability. Therefore, the Ni-spinel catalyst showed a good potential for H 2 production by APR of bio-oil aqueous fraction.

KW - Aqueous-phase reforming

KW - Bio-oil

KW - Hydrogen

KW - Ni-based catalysts

UR - http://www.scopus.com/inward/record.url?scp=85064626488&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2019.04.007

DO - 10.1016/j.ijhydene.2019.04.007

M3 - Article

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SN - 0360-3199

VL - 44

SP - 13157

EP - 13168

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 26

ER -

Aqueous-phase reforming of bio-oil aqueous fraction over nickel-based catalysts

Abstrakti

YK:n kestävän kehityksen tavoitteet

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

Biojalostamon vesivirtojen katalyyttinen vesifaasireformointi

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